Bis(dicyclohexylammonium) μ-oxalato-κ4O1,O2:O1′,O2′-bis[aqua(oxalato-κ2O1,O2)diphenylstannate(IV)]

被引：11
|
作者：
Gueye, Ndongo [1 ]
Diop, Libasse [1 ]
Molloy, K. C. Kieran [2 ]
Kociok-Koehn, Gabrielle [2 ]
机构：
[1] Univ Cheikh Anta Diop, Lab Chim Minerale & Analyt, Dept Chim, Fac Sci & Tech, Dakar, Senegal
[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
X-RAY STRUCTURE; CRYSTAL-STRUCTURE; COMPLEXES;
D O I：
10.1107/S1600536810046738
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structure of the title compound, (C12H24N)(2)[Sn-2(C6H5)(4)( C2O4)(3)(H2O)(2)], consists of a bischelating oxalate ion, located on an inversion center, which is linked to two SnPh2 groups. The coordination sphere of the Sn(IV) ion is completed by a monochelating oxalate anion and a water molecule. The Sn(IV) atoms are thus seven-coordinated. The discrete binuclear units are further connected by hydrogen bonds, leading to a supramolecular crystal structure. The asymmetric unit contains one half dianion and one (Cy2NH2)(+) cation.
引用
收藏
页码：M1645 / U1464
页数：12
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