Synthesis of Cu2ZnSnS4 monograin powders with different compositions

被引：33
|
作者：
Muska, K. [1 ]
Kauk, M. [1 ]
Altosaar, M. [1 ]
Pilvet, M. [1 ]
Grossberg, M. [1 ]
Volobujeva, O. [1 ]
机构：
[1] Tallinn Univ Techol, EE-19086 Tallinn, Estonia
来源：
EUROPEAN MATERIALS RESEARCH SOCIETY CONFERENCE SYMPOSIUM: ADVANCED INORGANIC MATERIALS AND CONCEPTS FOR PHOTOVOLTAICS | 2011年 / 10卷
关键词：
Cu2ZnSnS4; CZTS; composition; Raman;
D O I：
10.1016/j.egypro.2011.10.178
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The effect of changes in the composition ratios of Cu/(Zn+Sn) and Zn/Sn in initial precursor mixtures on the final composition and properties of Cu2ZnSnS4 (CZTS) monograin powders has been investigated. EDX studies revealed that Cu/(Zn+Sn) concentration ratios in the single phase powders can be changed only from 0.92 to 0.95 and Zn/Sn ratios only from 1.0 to 1.03. Raman spectra of all powders showed main peaks around 287, 338, and 375 cm(-1) characteristic for CZTS materials. Larger deviations from stoichiometry results in CZTS powder crystals with secondary phases, identified as Sn2S3, SnS2, Cu2-xS and ZnS. All CZTS monograins have p-type conductivity with an electrical resistance in the range of 1.3x10(3) to 1.6x10(4) Omega, depending on the initial composition of the precursor mixture. (C) 2011 Published by Elsevier Ltd. Selection and/or peer-review under responsibility of Organizers of European Materials Research Society (EMRS) Conference: Symposium on Advanced Inorganic Materials and Concepts for Photovoltaics.
引用
收藏
页数：5
相关论文
共 50 条
  • [41] Phase evolution and sintering behaviors of Cu2ZnSnS4 powders synthesized by mechanochemical process with different milling parameters
    Liu, Chao-Qian
    Wen, Bin
    Wang, Nan
    Liu, Shi-Min
    Wang, Hua-Lin
    Jiang, Wei-Wei
    Ding, Wan-Yu
    Xu, Shi-Chong
    Chai, Wei-Ping
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 708 : 428 - 436
  • [42] Preparations of Cu2ZnSnS4 thin films and Cu2ZnSnS4/Si heterojunctions on silicon substrates by sputtering
    Xu, Jiaxiong
    Yang, Yuanzheng
    Cao, Zhongming
    Xie, Zhiwei
    [J]. OPTIK, 2016, 127 (04): : 1567 - 1571
  • [43] Phase evolution and sintering behaviors of Cu2ZnSnS4 powders synthesized by mechanochemical process with different milling parameters
    [J]. Liu, Chao-Qian (cqliu@djtu.edu.cn), 1600, Elsevier Ltd (708):
  • [44] Synthesis and Structural Properties of Cu2ZnSnS4 and Cu Nanoparticles for Printed Electronics
    Pshenychnyi, Roman
    Volobuev, Vladislav
    Kolesnyk, Maxym
    Kurbatov, Denys
    Znamenshchykov, Yaroslav
    Opanasyuk, Anatoliy
    [J]. PROCEEDINGS OF THE 2019 IEEE 9TH INTERNATIONAL CONFERENCE ON NANOMATERIALS: APPLICATIONS & PROPERTIES (NAP-2019), PTS 1-2, 2019,
  • [45] Phase-controlled synthesis of Cu2ZnSnS4 powders via the microwave-assisted solvothermal route
    Lin, Yi-Hsung
    Das, Subrata
    Yang, Che-Yuan
    Sung, Jen-Cheng
    Lu, Chung-Hsin
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 632 : 354 - 360
  • [46] Phase-Selective Synthesis of Cu2ZnSnS4 Nanocrystals using Different Sulfur Precursors
    Li, Zhenggang
    Lui, Alvic Lim Kar
    Lam, Kwan Hang
    Xi, Lifei
    Lam, Yeng Ming
    [J]. INORGANIC CHEMISTRY, 2014, 53 (20) : 10874 - 10880
  • [47] Efficiency enhancement of Cu2ZnSnS4 monograin layer solar cells via absorber post-growth treatments
    Timmo, K.
    Sadurni, M. Dolcet
    Pilvet, M.
    Muska, K.
    Altosaar, M.
    Mikli, V.
    Atlan, F.
    Guc, M.
    Izquierdo-Roca, V.
    Grossberg-Kuusk, M.
    Kauk-Kuusik, M.
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2023, 250
  • [48] Solvothermal synthesis of Cu2ZnSnS4 nanocrystals by using metal oxides
    Peng, Xiaoli
    Guo, Wenbin
    Zhang, Shu
    Xiang, Yong
    [J]. 2014 INTERNATIONAL SYMPOSIUM ON NEXT-GENERATION ELECTRONICS (ISNE), 2014,
  • [49] Polyacrylic Acid Assisted Synthesis of Cu2ZnSnS4 by Hydrothermal Method
    Tiong, Vincent Tiing
    Hreid, Tubshin
    Will, Geoffrey
    Bell, John
    Wang, Hongxia
    [J]. SCIENCE OF ADVANCED MATERIALS, 2014, 6 (07) : 1467 - 1474
  • [50] Synthesis of Nonstoichiometric Cu2ZnSnS4 from ZnS by Cation Exchange
    Jin, Yi
    Chumanov, George
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (31) : 3761 - 3766
12345