Carbocyclic nucleoside precursors by intramolecular cyclopropanation of sugar-derived diazo compounds

被引:14
|
作者
Gallos, JK [1 ]
Massen, ZS [1 ]
Koftis, TV [1 ]
Dellios, CC [1 ]
机构
[1] Aristotelian Univ Thessaloniki, Dept Chem, GR-54006 Thessaloniki, Greece
关键词
D O I
10.1016/S0040-4039(01)01556-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Bicyclo[3.1.0]hexane derivatives, selectively prepared by intramolecular cyclopropanation of sugar-clerk ed unsaturated diazo compounds. are common precursors for the sugar moiety of cyclopentane. cyclopropane and bicyclo[3.1.0]hexane nucleosides. such as aristeromycin, the carbocyclic analogue of neplanocin C and the nucleoside A-5021. (C) 2001 Elsevier Science Ltd. All rights reserved.
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页码:7489 / 7491
页数:3
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