Letter: A simple ion source set-up for desorption/ionization on silicon with ion mobility spectrometry and ion mobility spectrometry-mass spectrometry

被引:5
|
作者
Adamov, Alexey [1 ,2 ]
Sysoev, Alexey A. [3 ,4 ]
Grigoras, Kestutis [5 ]
Laakia, Jaakko [1 ]
Kotiaho, Tapio [1 ,2 ]
机构
[1] Univ Helsinki, Analyt Chem Lab, Dept Chem, FI-00014 Helsinki, Finland
[2] Univ Helsinki, Div Pharmaceut Chem, Fac Pharm, FI-00014 Helsinki, Finland
[3] Natl Res Nucl Univ MEPhI, Moscow 115409, Russia
[4] Linantec Ltd, Moscow 115409, Russia
[5] Aalto Univ Sch Sci & Technol, Dept Micro & Nanosci, Espoo 02150, Finland
基金
芬兰科学院;
关键词
ion mobility spectrometry; desorption/ionization on silicon (DIOS); mass spectrometry; ENHANCED LASER DESORPTION/IONIZATION; ELECTROSPRAY-IONIZATION; POROUS SILICON;
D O I
10.1255/ejms.1157
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Using a simple ion source set-up, laser desorption/ionization on silicon (DIOS) was demonstrated with the use of a custom-made drift tube ion mobility spectrometer (IMS), mounted on a commercial triple quadrupole mass spectrometer, and with an IMS equipped with a Faraday plate detector. DIOS was tested by mobility measurement of tetrapropylammonium iodide, tetrabutylammonium iodide and tetrapentylammonium iodide, whilst 2,6-di-tert-butylpyridine was used as a standard. The reduced mobilities measured for the test halides are in concordance with previously obtained ion mobility spectrometry-mass spectrometry data.
引用
收藏
页码:593 / 597
页数:5
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