Cross-Coupling of Aryl/Alkenyl Ethers with Aryl Grignard Reagents through Nickel-Catalyzed C-O Activation

被引：87
|
作者：
Xie, Lan-Gui [1 ,2 ]
Wang, Zhong-Xia [1 ,2 ]
机构：
[1] Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 18期
基金：
中国国家自然科学基金;
关键词：
C-O activation; cross-coupling; Grignard reagents; homogeneous catalysis; nickel; CARBON-CARBON BONDS; UNSYMMETRICAL BIARYLS; ORGANOBORON COMPOUNDS; EFFICIENT SYNTHESIS; OXYGEN; CONSTRUCTION; ALKENYL; HALIDES; OLEFINS; ARENES;
D O I：
10.1002/chem.201003731
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The formation of a C-C bond has been achieved through the cleavage of the sp2 C-O bond of aryl/alkenyl ethers catalyzed by a nickel complex, and by using Grignard reagents as nucleophiles (see scheme). This method displays a broad substrate scope and leads to good to excellent yields of the aryl-aryl or alkenyl-aryl cross-coupling products. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4972 / 4975
页数：4
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