Synthesis of new chiral 1,2-disubstituted ferrocenes

被引：6

作者：

Fleischer, I ^{[1
]}

Toma, S ^{[1
]}

机构：

[1] Comenius Univ, Fac Nat Sci, Dept Organ Chem, SK-84215 Bratislava, Slovakia

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 2004年 / 69卷 / 02期

关键词：

ferrocenes; planar chirality; diastereoselective reactions; ferrocenecarbaldehydes; pyrrolidines; oxidations;

D O I：

10.1135/cccc20040330

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of six chiral 1,2-disubstituted ferrocene derivatives is described starting from (S)-{[2-(methoxymethyl) pyrrolidin-1-yl] methyl} ferrocene (2) and {[N-((1R, 2S)-methoxy-1- methyl-2-phenethyl)-N-methylamino] methyl} ferrocene (3). Oxidation of the (N- substituted aminomethyl) ferrocenes with active MnO2 furnished the corresponding 2- substituted ferrocenecarbaldehydes.

引用

页码：330 / 338

页数：9

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