A novel CdII coordination polymer with 1,1′-(1,4-butanediyl)diimidazole

被引:3
|
作者
Ma, JF [1 ]
Yang, J [1 ]
Liu, JF [1 ]
机构
[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China
关键词
D O I
10.1107/S0108270103022443
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The novel title Cd-II coordination polymer, poly[[dichlorocadmium(II)]-di-mu-1,1'-(1,4-butanediyl)diimidazole], [CdCl2(C10H14N4)(2)](n), (I), was obtained by reaction of CdCl2.2.5H(2)O and 1,1'-(1,4-butanediyl)diimidazole (hereafter L). In (I), each L molecule coordinates to two Cd-II cations through its two aromatic N atoms, thus acting as a bridging bidentate ligand. The Cd-II cations, which lie on the inversion centre, are bridged by four L molecules to form a two-dimensional (4,4)-network. The two-dimensional square-grid sheets are superimposed in an offset fashion.
引用
收藏
页码:M482 / M483
页数:2
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