Experimental and quantum-chemical investigation of thermolysis of adamantyl-substituted organosilicon peroxides

被引：0
|
作者：
Nho, BI
Butov, GM
Dumskii, SY
Sabirov, ZM
Urazbaev, VN
Monakov, YB
机构：
[1] Russian Acad Sci, Ufa Res Ctr, Inst Organ Chem, Ufa 450054, Russia
[2] Volgograd State Tech Univ, Volgograd 400066, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 07期
关键词：
adamantane; organosilicon peroxides; thermolysis; MNDO;
D O I：
10.1007/BF02495547
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The kinetics and mechanism of thermal decomposition of adamantyl-containing organosilicon peroxides in a solution in n-nonane were studied. The relationship between the structure of the peroxide and the rate and mechanism of thermalysis was established. The effect of the peroxide structure on the electronic characteristics of the peroxide band was studied by the MNDO method. The heterolytic rearrangement occurring during the decomposition of peroxides was analyzed.
引用
收藏
页码：1280 / 1283
页数：4
相关论文
共 50 条
  • [21] Methyl phenyl sulfide: Quantum-chemical investigation
    Bzhezovskii, VM
    Kapustin, EG
    Il'chenko, NN
    Kulik, NI
    Gorb, LG
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2000, 70 (11) : 1766 - 1778
  • [22] QUANTUM-CHEMICAL CALCULATION OF THE DISASSOCIATION ENERGY OF HOMONUCLEAR BONDS IN ORGANIC PEROXIDES AND HYDRAZINES
    VYSHINSKII, NN
    KOKOREV, VN
    KULIKOVA, GP
    ABRONIN, IA
    ALEXANDROV, IA
    ZHIDOMIROV, GM
    MASLENNIKOV, VP
    DOKLADY AKADEMII NAUK SSSR, 1980, 250 (05): : 1140 - 1144
  • [23] QUANTUM-CHEMICAL ANALYSIS OF FORMATION OF CROSSLINKED STRUCTURES AND VOLATILE PRODUCTS IN THERMOLYSIS OF POLYIMIDES
    YAKIMANSKII, AV
    MILEVSKAYA, IS
    ZUBKOV, VA
    YELYASHEVICH, AM
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1989, 31 (11): : 2318 - 2321
  • [24] A Quantum-Chemical Investigation of the Geometry and NMR Chemical Shifts of Bilirubin
    T. Metzroth
    M. Lenhart
    J. Gauss
    Applied Magnetic Resonance, 2008, 33 : 457 - 467
  • [25] A quantum-chemical investigation of the geometry and NMR chemical shifts of bilirubin
    Metzroth, T.
    Lenhart, M.
    Gauss, J.
    APPLIED MAGNETIC RESONANCE, 2008, 33 (04) : 457 - 467
  • [26] o-Benzoquinone Cobalt Complexes Bearing Organosilicon Radicals: Quantum-Chemical Study
    A. A. Starikova
    M. G. Chegerev
    A. G. Starikov
    V. I. Minkin
    Russian Journal of Coordination Chemistry, 2022, 48 : 233 - 241
  • [27] o-Benzoquinone Cobalt Complexes Bearing Organosilicon Radicals: Quantum-Chemical Study
    Starikova, A. A.
    Chegerev, M. G.
    Starikov, A. G.
    Minkin, V. I.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2022, 48 (04) : 233 - 241
  • [28] QUANTUM-CHEMICAL DETERMINATION OF THE AL-SUBSTITUTED SITE IN TOBERMORITE
    KASHIHARA, S
    YAMANAKA, S
    INOUE, T
    KOMATSU, T
    TOYOSHIMA, H
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1994, 77 (11) : 3023 - 3026
  • [29] Acidity of substituted hydrofullerenes: An ab initio quantum-chemical study
    Van Lier, G
    Safi, B
    Geerlings, P
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1997, 58 (11) : 1719 - 1727
  • [30] Quantum-chemical investigation of reactions of (dialkylamino)ethynylphosphonates with amines
    Semenov, S. G.
    Aleksandrova, A. V.
    Dogadina, A. V.
    Sigolaev, Yu. F.
    Belyakov, A. V.
    Ionin, B. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2006, 76 (06) : 895 - 905
12345