Flexible Metal-Organic Framework with Hydrophobic Pores

被引：57

作者：

Xie, Lin-Hua ^{[1
]}

Suh, Myunghyun Paik ^{[1
]}

机构：

[1] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 49期

基金：

新加坡国家研究基金会;

关键词：

flexible networks; gas sorption; hydrophobic effect; metal-organic frameworks; stepwise adsorption; COORDINATION POLYMER; PALLADIUM NANOPARTICLES; WATER-ADSORPTION; GAS SEPARATION; SORPTION; CAPTURE; NETWORK; SILVER;

D O I：

10.1002/chem.201103078

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ready for the plunge: A metal-organic framework with channels of approximately 6 Å in diameter lined with tert-butyl groups was synthesized (see picture). The structure shrinks after guest removal, and results in a highly hydrophobic porous material, which reversibly adsorbs most common gases (N2, O2, CO2, H2 and CH 4), but essentially shows no uptake of water under saturated water vapour pressure at room temperature. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：13653 / 13656

页数：4

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