Absolute charge transfer and fragmentation cross sections in He2++C60 collisions

被引:2
|
作者
Diaz-Tendero, S. [1 ,2 ,3 ]
Ruiz, L. F. [3 ]
Zarour, B. [4 ]
Hanssen, J. [4 ]
Alcami, M.
Politis, M. F. [5 ]
Hervieux, P-A [6 ]
Martin, F. [3 ]
机构
[1] CNRS, Lab Collis Atom & Mol, UMR 8625, Batiment 351, F-91405 Orsay, France
[2] Univ Paris 11, UMR 8625, Lab Collisions Atomiques Moleculaires, F-91405 Orsay, France
[3] Univ Autonoma Madrid, Departamento Quim, E-28049 Madrid, Spain
[4] Univ Metz, LPMC, F-57078 Metz 03, France
[5] Univ Paris 06, IMPMC, F-75015 Paris, France
[6] Inst Phys Chimie Materiaux Strasbourg, F-67034 Strasbourg, France
关键词
IONIZATION-POTENTIALS; DISSOCIATION-ENERGIES; C-60; MOLECULE; IONS; EXCITATION; CLUSTERS; EXCHANGE; HE2+;
D O I
10.1088/1742-6596/194/1/012047
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
We present a set of theoretical methods to study the different processes taking place in ion-fullerene collisions. In particular, we focus on charge transfer, excitation and fragmentation processes. These methods have been successfully applied to the case of He2+ + C-60 collisions. We have found that single and double charge transfer cross sections are of the same order of magnitude in the velocity range studied (impact energy similar to 0.1 - 10 keV). Fragmentation of C-60(+) into C-58(+)+C-2 is observed only with large excitation energies and/or if one waits long enough (detecting the fragments at large distances from the collision). The agreement between our predictions and the experimental results supports the validity of the methods presented.
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收藏
页数:8
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