Facile and Mild Process for Chemical Fixation of CO2 to 4-Methylene-1,3-oxazolidin-2-ones Under Solvent-Free Conditions

被引：10
|
作者：
Xu, Jingxiu [1 ]
Zhao, Jinwu [1 ]
Jia, Zhenbin [1 ]
Zhang, Jianhe [1 ]
机构：
[1] Guangdong Med Coll, Sch Pharm, Dongguan, Peoples R China
来源：
SYNTHETIC COMMUNICATIONS | 2011年 / 41卷 / 06期
关键词：
Carbon dioxide; chemical fixation; oxazolidinone; propargylic alcohol; solvent-free; ECO-FRIENDLY PROCESS; BETA-AMINO ALCOHOLS; CARBON-DIOXIDE; CHIRAL AUXILIARIES; OXAZOLIDINONES; CATALYSTS; EFFICIENT; 2-OXAZOLIDINONES; CARBONYLATION; COMPLEXES;
D O I：
10.1080/00397911003707014
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[image omitted] 4-Methylene-1,3-oxazolidin-2-ones were prepared via the cycloadditon reaction of propargylic alcohols with primary amines and CO2 under atmospheric pressure at 60 degrees C in the absence of any additional solvent. This methodology affords an ecofriendly, mild, and easy approach to chemical fixation of CO2.
引用
收藏
页码：858 / 863
页数：6
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