Synthesis, structure and magnetic properties of [Cu4(Hmbpp)2(H2NC(O)NH2)2(H2O)8]•4H2O

被引：4
|
作者：
Harrison, A
Henderson, DK
Lovatt, PA
Parkin, A
Tasker, PA
Winpenny, REP
机构：
[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
[2] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
来源：
DALTON TRANSACTIONS | 2003年 / 22期
关键词：
D O I：
10.1039/b309475h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cu-4(Hmbpp)(2)(H2NC(O)NH2)(2)(H2O)(8)] . 4H(2)O 1, the first example of a discrete polynuclear copper phosphonate complex isolated from aqueous media was synthesised by the addition of urea to a solution of a copper(II) salt and the bisphosphonic acid ligand 4-methyl-2,6-bis(phosphonomethyl) phenol (H(5)mbpp). 1 contains four distorted square pyramidal copper atoms and the Cu-4 units are linked by a complicated hydrogen bonded network involving co-crystallised water molecules.
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页码：4271 / 4274
页数：4
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