Recovery of Glass Fibers from Fiber Reinforced Plastics

被引:18
|
作者
Shima, Hideki [1 ]
Takahashi, Hiroo [1 ]
Mizuguchi, Jin [1 ]
机构
[1] Yokohama Natl Univ, Grad Sch Engn, Dept Appl Phys, Yokohama, Kanagawa 2408501, Japan
关键词
fiber reinforced plastic; recycle; thermal activation of semiconductors; chromium oxide; nickel oxide; titanium dioxide; alpha-hematite; THERMALLY-EXCITED HOLES; COMPLETE DECOMPOSITION; TITANIUM-DIOXIDE; HIGH-TEMPERATURES; GENERATED HOLES; TIO2;
D O I
10.2320/matertrans.M2011044
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Recovery of glass fibers from fiber reinforced plastics (FRP) has been tackled by our novel technology based upon thermally activated semiconductors such as Cr2O3, NiO, TiO2, and alpha-Fe2O3. This is a scientifically proven technology which utilizes a vast number of thermally-generated oxidative holes for instantaneous decomposition of filler-free thermoplastic or thermosetting polymers. No shredding or grinding of the scrap FRP is necessary in the present system, nor is the use of organic solvents. FRP plates were simply placed in contact with powdered Cr2O3 and heated at about 350-500 degrees C. As soon as the FRP was sufficiently heated, the polymer matrix began to decompose into H2O and CO2, leaving behind only glass fibers without any deterioration of their quality. The glass fibers were perfectly recovered, exactly in the original form of "chopped strand mat". Our system can recover glass fibers as well as thermal energy. [doi:10.2320/matertrans.M2011044]
引用
收藏
页码:1327 / 1329
页数:3
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