Oxidation-Reduction of Maleic Acid Induced by Argon-Hydrogen Plasma-Jet

被引：1

作者：

Yamakawa, Isao ^{[2
]}

Ito, Yoshimi ^{[2
]}

Munegumi, Toratane ^{[1
]}

Harada, Kaoru ^{[2
]}

机构：

[1] Oyama Natl Coll Technol, Dept Mat Chem & Bioengn, Nakakuki, Oyama 3230806, Japan

[2] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2010年 / 83卷 / 10期

关键词：

GLOW-DISCHARGE ELECTROLYSIS; AQUEOUS-SOLUTION; ARC PLASMA; HYDROXYLATION;

D O I：

10.1246/bcsj.20100079

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Plasma-jet in aqueous solutions is known to disproportionate water to give hydrogen and hydroxyl radicals. Maleic acid, which is a carbon carbon double bond bearing dicarboxylic acid, underwent addition of hydrogen, hydrogen plus hydroxyl, hydroxyl species under an argon hydrogen plasma-jet. Maleic acid (10mM) yielded 42% succinic acid (dihydrogenated product) under an argon-hydrogen (1.5 and 0.5 L min(-1)) plasma-jet. This demonstrates an effective reduction method for maleic acid by plasma-jet in aqueous solutions.

引用

页码：1264 / 1268

页数：5

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