Crystal structure, Mossbauer spectra, and thermal behavior of H2Fe(CO)2[P(OPh)3]2

被引：13
|
作者：
Arion, V
Brunet, JJ [1 ]
Neibecker, D
机构：
[1] Univ Toulouse 3, CNRS Unite 8241, Chim Coordinat Lab, F-31077 Toulouse, France
[2] Inst Natl Polytech, F-31077 Toulouse, France
来源：
INORGANIC CHEMISTRY | 2001年 / 40卷 / 11期
关键词：
D O I：
10.1021/ic0006899
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first crystallographic characterization of an iron carbonyl dihydride H2Fe(CO)(2)[P(OPh)(3)](2) has been performed. The complex has a distorted octahedral geometry with two triphenylphosphite ligands trans to each other and the carbonyl ligands cis to each other. The two other equatorial sites are occupied by two cis hydrides. Mossbauer spectra and thermal behavior of H2Fe(CO)(2)[P(OPh)(3)](2) are also reported and compared with those of related complexes.
引用
收藏
页码：2628 / +
页数：4
相关论文
共 50 条
  • [31] REACTIONS OF CPMO(CO)2[P(OPH)3]CH2OCH3 WITH ELECTROPHILES
    GIBSON, DH
    FRANCO, JO
    RICHARDSON, JF
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 117 - INOR
  • [32] CRYSTAL-STRUCTURE OF TRANS-FE(CO)3[P(OCH3)3]2
    GINDEROW, D
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, 30 (DEC15): : 2798 - 2802
  • [33] Arylisocyanide derivatives of iron(0):: crystal and molecular structures of Fe(CO)2[P(OPh)3]2(CNR) (R = phenyl, para-tolyl, mesityl)
    Cromhout, NL
    Gallagher, JF
    Lough, AJ
    Manning, AR
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2002, 217 (7-8): : 401 - 405
  • [34] Crystal structure of [{MoBr2(O){OPH(OPri)2}2}2(μ-O)]
    Baker, PK
    Drew, MGB
    Meehan, MM
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2001, 31 (9-10) : 407 - 410
  • [35] A REFINEMENT OF CRYSTAL STRUCTURE OF NA2CO3.H2O
    DICKENS, B
    MAUER, FA
    BROWN, WE
    JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS SECTION A-PHYSICS AND CHEMISTRY, 1970, A 74 (03): : 319 - +
  • [36] Crystal structure and Raman spectra of [Fe(H2O)6]3+(ClO4−)3·3H2O
    L. S. Skogareva
    G. V. Shilov
    A. I. Karelin
    Journal of Structural Chemistry, 2012, 53 : 907 - 914
  • [37] Crystal structure and Raman spectra of [Fe(H2O)6]3+(ClO4-)3•3H2O
    Skogareva, L. S.
    Shilov, G. V.
    Karelin, A. I.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 53 (05) : 907 - 914
  • [38] SYNTHESIS AND CRYSTAL STRUCTURE OF Fe-3(CO)(8)[P(SC6H5)Cl-2(mu(3)-S)(2)
    Liu Qiwang
    Liu Shutang
    Wu Binfang
    Suo Quanling
    Hu Xiang
    Wang Beyi
    ACTA PHYSICO-CHIMICA SINICA, 1990, 6 (06) : 730 - 734
  • [39] Crystal structure of [{MoBr2(O){OPH(OPri)2}2}2(μ-O)]
    Paul K. Baker
    Michael G.B. Drew
    Margaret M. Meehan
    Journal of Chemical Crystallography, 2001, 31 : 407 - 410
  • [40] [FE(CO)2(P(OPH)3)2(CS)] - 1ST STABLE THIOCARBONYL DERIVATIVE OF IRON(0) PENTACARBONYL
    CONWAY, P
    MANNING, AR
    STEPHENS, FS
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 186 (03) : C64 - C66
12345