Unprecedented magnetic behaviour in lanthanide-based ionic liquids

被引：8

作者：

Monson, Todd C. ^{[1
]}

Stevens, Tyler E. ^{[1
]}

Leger, Jean L. ^{[1
]}

Manson, Jamie L. ^{[2
]}

Lovejoy, Katherine S. ^{[3
]}

Newsham, Aimee L. ^{[4
]}

Del Sesto, Rico E. ^{[4
]}

机构：

[1] Sandia Natl Labs, Nanoscale Sci, POB 5800, Albuquerque, NM 87185 USA

[2] Eastern Washington Univ, Dept Chem & Biochem, Cheney, WA 99004 USA

[3] Los Alamos Natl Lab, Mat Chem, POB 1663,MS J514, Los Alamos, NM 87545 USA

[4] Dixie State Univ, Dept Phys Sci, St George, UT 84770 USA

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 85期

关键词：

DYNAMICS; SUSCEPTIBILITY; TEMPERATURE; SOLVENTS;

D O I：

10.1039/c7cc07060h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionic liquids containing lanthanide halide anions give the opportunity to investigate magnetic behaviour in non-ordered systems. Reported herein is the synthesis and characterization of ionic liquids containing a series of lanthanide halide anions, with the resulting materials displaying unusual behaviour below 50 K. Specifically, the ionic liquid structural glass formation appears to drive magnetic behaviour due to cluster formation of the anions during rapid cooling. This system presents a possible probe to study the dynamics of glass forming materials.

引用

页码：11682 / 11685

页数：4

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