A polyhedral magnesium silicate with a Mg5Si4O10 framework:: X-ray crystal structure of [{(2,6-i-Pr2C6H3)N(SiMe3SiMe3)SiO3}2-{(2,6-i-Pr2C6H3)N(SiMe3)SiO2(OH)}2(Mg•C4H8O)5]

被引：8
|
作者：
Klemp, A [1 ]
Roesky, HW [1 ]
Schmidt, HG [1 ]
Park, HS [1 ]
Noltemeyer, M [1 ]
机构：
[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany
来源：
ORGANOMETALLICS | 1998年 / 17卷 / 24期
关键词：
D O I：
10.1021/om980501h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction, of (2,6-i-Pr(2)C(6)H3)N(SiMe3)Si(OH)(3) (1) with Bu2Mg in THF at room-temperature resulted in the formation of the magnesium silicate 2. The core of the molecule consists of two four-membered, two six-membered, and three eight-membered rings and can be regarded as a molecular magnesium silicate soluble in conventional organic solvents.
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收藏
页码：5225 / 5227
页数：3
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