Partially oxidized Zintl ions?: The characterization of [(μ3-OH)(μ3-O)3(OEt)3{(CO)5W}7Sn7]2-

被引：0
|
作者：
Kircher, P [1 ]
Huttner, G [1 ]
Zsolnai, L [1 ]
Driess, A [1 ]
机构：
[1] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1998年 / 37卷 / 12期
关键词：
cage compounds; tin; tungsten; Zintl anions;
D O I：
10.1002/(SICI)1521-3773(19980703)37:12<1666::AID-ANIE1666>3.0.CO;2-V
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A formally isoelectronic (μ3-Sn)2- ion replaces the μ3-O building block in the subvalent anion 1, which is a derivative of the known cage compound [(μ3-OR)4(μ3-O)4Sn6]. Thus, compound 1 forms a link between oxo metal clusters and Zint1 ions. [(μ3-OH)(μ3-O)3(OEt)3{(CO)5W}7Sn7]2- 1.
引用
收藏
页码：1666 / 1668
页数：3
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