Heterocyclic reactive mesogens: synthesis, characterisation and mesomorphic behaviour

被引:73
|
作者
Aldred, MP
Vlachos, P
Dong, DW
Kitney, SP
Tsoi, WC
O'Neill, M
Kelly, SM
机构
[1] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England
[2] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China
[3] Univ Hull, Dept Phys, Kingston Upon Hull HU6 7RX, N Humberside, England
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1080/02678290500248400
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel heterocyclic and photopolymerizable liquid crystalline materials ( reactive mesogens) with smectic phases have been synthesized and characterized. A selection of heterocyclic rings, such as benzothiazole, benzothiadiazole and pyrimidine, has been incorporated into the aromatic core to control the electrochemical/luminescence properties and the structural geometry. Particular emphasis is focused on structure - property relationships, in which the variation of molecular structure and its subsequent effect on the liquid crystalline transition temperatures have been investigated.
引用
收藏
页码:951 / 965
页数:15
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