Contrasting effects of soil development on hydrological properties and flow paths

[1] Runoff pathways strongly influence hydrologic and biogeochemical losses and landscape evolution. On an evolving landscape, soil development may alter hydrologic properties and thereby change through time the relative importance of various pathways. Here we report in situ soil water retention, unsaturated and saturated hydraulic conductivity, and flow path characteristics of a 300 year old Andisol and a 4.1 million year old Oxisol, located at the extreme ends of a soil substrate age gradient across the Hawaiian Islands. The two soils contrasted in depth and texture; the young soil was shallow and coarse textured, while the old soil was deep and highly weathered with a near-surface plinthite horizon overlying numerous clay-rich subsurface horizons. The young soil drained freely under modest suction, whereas subsurface clay horizons at the old site required significantly more suction to start to drain than the upper horizons. Similarly, saturated hydraulic conductivity (K-s) was high throughout the soil profile at the young site, whereas K-s was two to three orders of magnitude lower through the subsurface clay horizons than the upper ones at the old site. Irrigation experiments with deuterium tracer demonstrated that water was downward advecting at the young site, while water at the old site moved both laterally along the subsurface clay horizon contact and slowly downward through it. Rainfall frequency distributions indicated a high probability of rainfall events exceeding subsurface K-s values in old soil. In Hawaii the addition of dust influences the time evolution of soil, but the tendency for subsoil clay accumulation in older soils leading to alteration in hydrologic flow paths has been proposed in other environments. Our findings together suggest that as soils develop with time, subsurface horizon Ks values decline, impeding rates of vertical water flow but also increasing the importance of shallow subsurface lateral flow.