Synthesis of homopropargyl alcohols via sonochemical Barbier-type reaction

被引：36

作者：

Lee, ASY ^{[1
]}

Chu, SF ^{[1
]}

Chang, YT ^{[1
]}

Wang, SH ^{[1
]}

机构：

[1] Tamkang Univ, Dept Chem, Tamsui 251, Taiwan

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 07期

关键词：

D O I：

10.1016/j.tetlet.2003.12.058

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of homopropargyl alcohols were synthesized from the reaction mixture of zinc powder, 1,2-diiodoethane, 3-bromo-1-propyne and aldehyde or ketone in anhydrous THF under ultrasound. The homopropargyl alcohols were obtained as the only product in all cases when aldehydes were reacted with 3-bromo-1-propyne under this sonochemical Barbier-type reaction condition. The homopropargyl alcohol was produced as the major product and the low contamination of allenyl alcohol was also obtained when ketone was used as substrate under the reaction condition. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：1551 / 1553

页数：3

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