Growth, thermal and optical properties of r-2,c-6-bis(p-tolyl)-c-3,t-3-dimethylpiperidin-4-one - A new class of organic NLO material

被引：0
|
作者：
Mohanraj, V [1 ,2 ]
Karthik, K. [1 ,3 ]
Ilango, S. S. [1 ]
Ponnuswamy, S. [1 ]
机构：
[1] Govt Arts Coll Autonomous, PG & Res Dept Chem, Coimbatore 641018, Tamil Nadu, India
[2] Govt Arts & Sci Coll, Dept Chem, Kanyakumari 629701, India
[3] Kumaraguru Coll Technol Autonomous, Dept Chem, Coimbatore 641049, Tamil Nadu, India
来源：
MATERIALS TODAY-PROCEEDINGS | 2022年 / 62卷
关键词：
Growth; Solubility; r-2; c-6-bis(p-tolyl)-c-3; t-3-dimethylpiperidin-4-one; powder XRD; Nonlinear optical properties;
D O I：
10.1016/j.matpr.2022.03.390
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
An organic nonlinear optical crystal, r-2,c-6-bis(p-tolyl)-c-3,t-3-dimethylpiperidin-4-one (PT3DMPO), was synthesized using ammonium acetate, p-methyl benzaldehyde, methyl isopropyl ketone and ethanol. The PT3DMPO crystals were grown using slow evaporation method. Spectroscopic techniques like FTIR, UV Visible, Powder XRD, H-1 NMR, C-13 NMR were employed to characterise the grown single crystals. The non-centro symmetric crystal was found to be orthorhombic system with Pna2 1 space group. Thermogravimetry and differential thermal analysis techniques were employed to analyse the thermal stability of PT3DMPO and found that the title compound is stable up to 375 degrees C. Using Kurtz - Perry powder method, the second harmonic generation efficiency was determined for the compound and found to have almost equal (0.95 times) efficiency as that of standard potassium dihydrogen orthophosphate (KDP). Copyright (C) 2022 Elsevier Ltd. All rights reserved.
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收藏
页码：5323 / 5328
页数：6
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