Molecular shape selectivity of hydrotalcite in mixed aldol condensations of aldehydes and ketones

被引：11
|
作者：
Cerveny, Jaroslav [1 ]
Splichalova, Jana [1 ]
Kacer, Petr [1 ]
Kovanda, Frantisek [2 ]
Kuzma, Marek [3 ]
Cerveny, Libor [1 ]
机构：
[1] Inst Chem Technol, Dept Organ Technol, CR-16628 Prague 6, Czech Republic
[2] Inst Chem Technol, Dept Solid State Chem, CR-16628 Prague 6, Czech Republic
[3] Acad Sci Czech Republ, Inst Microbiol, CR-14220 Prague 4, Czech Republic
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2008年 / 285卷 / 1-2期
关键词：
hydrotalcite; aldol condensation; molecular modeling;
D O I：
10.1016/j.molcata.2008.01.029
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The work has engaged in the effect of activated hydrotalcite for aldol condensation of cyclic and linear ketones with n-heptanal and norborn-5-ene-2-carbaldehyde. A significant configuration selectivity of the catalyst was found, when the condensation of the cyclic ketones was strongly prefered in comparison with condensation of the linear ones. The mechanism of the surface reaction was predicted by the methods of molecular modeling. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：150 / 154
页数：5
相关论文
共 50 条
  • [21] Aldol condensations catalysed by novel Mg-Al-O-t-Bu hydrotalcite
    Choudary, BM
    Kantam, ML
    Kavita, B
    Reddy, CV
    Rao, KK
    Figueras, F
    TETRAHEDRON LETTERS, 1998, 39 (21) : 3555 - 3558
  • [22] AN ALDOL CONDENSATION EXPERIMENT USING A NUMBER OF ALDEHYDES AND KETONES
    HATHAWAY, BA
    JOURNAL OF CHEMICAL EDUCATION, 1987, 64 (04) : 367 - 368
  • [23] REGIOSPECIFIC DIRECTED ALDOL REACTIONS OF METHYL KETONES WITH ALDEHYDES
    KUWAJIMA, I
    SATO, T
    ARAI, M
    MINAMI, N
    TETRAHEDRON LETTERS, 1976, (21) : 1817 - 1820
  • [24] Regioselectivity and chemoselectivity in heterogeneously catalyzed cross-aldol condensations with unsymmetrical ketones
    Ponnuru, Koushik
    Manayil, Jinesh C.
    Cho, Hong Je
    Osatiashtiani, Amin
    Fan, Wei
    Wilson, Karen
    Jentoft, Friederike
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [25] The Influence of β-Ammonium Substitution on the Reaction Kinetics of Aminooxy Condensations with Aldehydes and Ketones
    Ogunwale, Mumiye A.
    Knipp, Ralph J.
    Evrard, Clint N.
    Thompson, Lee M.
    Nantz, Michael H.
    Fu, Xiao-An
    CHEMPHYSCHEM, 2019, 20 (06) : 815 - 822
  • [26] Triple-component condensations of hetarylguanidines with aldehydes (ketones) and dicarbonyl compounds
    Potapov, A. Yu.
    Shikhaliev, Kh. S.
    Krylski, D. V.
    Krisin, M. Yu.
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 2006, (10): : 1549 - 1554
  • [27] Doubly Vinylogous Aldol Reaction of Furoate Esters with Aldehydes and Ketones
    Hartwig, William T.
    Sammakia, Tarek
    JOURNAL OF ORGANIC CHEMISTRY, 2017, 82 (01): : 759 - 764
  • [28] Ruthenium-catalyzed cross aldol reaction with aldehydes and ketones
    Tabatabaeian, Khalil
    Mamaghani, Manouchehr
    Mahmoodi, Nosrat O.
    Keshavarz, Elahe
    ARKIVOC, 2009, : 68 - 75
  • [29] Direct catalytic asymmetric aldol reactions of aldehydes with unmodified ketones
    Graduate Sch. of Pharmaceut. Sci., University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113, Japan
    Angew Chem (Int Ed Engl), 17 (1871-1873):
  • [30] Aldol condensation of aldehydes and ketones over solid base catalysts
    Kelly, GJ
    Jackson, SD
    CATALYSIS IN APPLICATION, 2003, : 129 - 135
12345