Monitoring Thermally Induced Cylindrical Microphase Separation of Polystyrene-block-poly(methyl methacrylate) by Atomic Force Microscopy

被引：0

作者：

Hiroshiba, Nobuya ^{[1
]}

Okubo, Ryo ^{[1
]}

Hattori, Azusa N. ^{[2
]}

Tanaka, Hidekazu ^{[2
]}

Nakagawa, Masaru ^{[1
]}

机构：

[1] Tohoku Univ, IMRAM, Aoba Ku, 2-1-1 Katahira, Sendai, Miyagi 9808577, Japan

[2] Osaka Univ, ISIR, Mihogaoka 8-1, Osaka 5670047, Japan

来源：

JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY | 2016年 / 29卷 / 05期

关键词：

block copolymer lithography; polystyrene-block-poly(methyl methacrylate); cylindrical microphase separation; PS-B-PMMA; BLOCK-COPOLYMER FILMS; THIN-FILMS; DIBLOCK COPOLYMERS; NANOSTRUCTURES; ARRAYS; REORGANIZATION; ORIENTATION; MORPHOLOGY; RESIST;

D O I：

10.2494/photopolymer.29.659

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Thermally induced growth of cylindrical microphase separation was observed for polystyrene-block-poly(methyl methacrylate) (PS-b-PMMA) thin films on native oxide silicon substrates unmodified and modified with hydroxy-terminated polystyrene (PS-OH) by atomic force microscopy in dynamic force mode. The degrees of long-range order of the cylindrical microphase separation structures were investigated using the correlation length values. The correlation length became constant over 30 seconds regardless of the kind of substrates, while the PS-OH modified substrate caused a longer correlation length and a shorter closely packed periodicity in the cylindrical microphase separation than the bare silicon substrate did.

引用

页码：659 / 665

页数：7

共 50 条

[1] An observation on the microphase separation of poly(methyl methacrylate)-block-polystyrene copolymer
Deng, J
Li, XS
Wang, ZM
Shao, G
Liu, JZ
[J]. CHINESE CHEMICAL LETTERS, 2001, 12 (05) : 467 - 470
[2] An Observation on the Microphase Separation of Poly(methyl methacrylate)-block-Polystyrene Copolymer
Jie DENG
[J]. Chinese Chemical Letters, 2001, (05) : 467 - 470
[3] Morphology of poly styrene/polystyrene-block-poly(methyl methacrylate)/poly(methyl methacrylate) composite particles
Okubo, M
Saito, N
Takekoh, R
Kobayashi, H
[J]. POLYMER, 2005, 46 (04) : 1151 - 1156
[4] Molecular dynamics simulation of polystyrene-block-poly(methyl methacrylate)
Lu, ZY
Li, ZS
Huang, XR
Jiang, BZ
Sun, JZ
[J]. MACROMOLECULAR THEORY AND SIMULATIONS, 1998, 7 (06) : 619 - 622
[5] Nanohole Structure Prepared by a Polystyrene-block-poly(methyl methacrylate)/poly(methyl methacrylate) Mixture Film
Joo, Wonchul
Yang, Seung Yun
Kim, Jin Kon
Jinnai, Hiroshi
[J]. LANGMUIR, 2008, 24 (21) : 12612 - 12617
[6] The block length effect of polystyrene-block-poly(methyl methacrylate) on the interfacial adhesion between polystyrene-poly(methyl methacrylate) and between polystyrene/phenoxy
Cho, JC
Kim, KH
Jo, WH
[J]. POLYMER JOURNAL, 1996, 28 (12) : 1060 - 1064
[7] Enhancing the PLA Crystallization Rate by Incorporating a Polystyrene-block-Poly( methyl methacrylate) Block Copolymer: Synergy of Polystyrene and Poly( methyl methacrylate) Segments
Wu, Chien-Pang
Wang, Cheng-Chien
Chen, Chuh-Yung
[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2014, 52 (12) : 823 - 832
[8] Chemical composition effects on the fracture of polystyrene-block-poly(methyl methacrylate) block copolymers
Kim, Won
Han, Junwon
Ryu, Chang Y.
Yang, Hoichang
[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2006, 44 (24) : 3612 - 3620
[9] Preparation of Special Microstructures by Polystyrene-Block-Poly(methyl methacrylate) Surface Micelles
Hong, Xiaodong
Liang, Bing
[J]. MATERIALS AND MANUFACTURING, PTS 1 AND 2, 2011, 299-300 : 621 - +
[10] Syndiotactic Polystyrene-block-Poly(methyl methacrylate) Copolymer via Click Chemistry
Capacchione, Carmine
De Roma, Antonella
Buonerba, Antonio
Speranza, Vito
Milione, Stefano
Grassi, Alfonso
[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2013, 214 (17) : 1990 - 1997

← 1 2 3 4 5 →