Crystal and molecular structure of trans-[IrCl(N2)(PiPr3)2]

被引：5

作者：

Boettcher, Hans-Christian ^{[1
]}

Graf, Marion ^{[1
]}

Mayer, Peter ^{[1
]}

Suenkel, Karlheinz ^{[1
]}

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 08期

关键词：

iridium; phosphane; dinitrogen complex; crystal structure;

D O I：

10.1002/zaac.200800074

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of trans-[IrCl(N-2)((PPr3)-Pr-i)(2)] (1), obtained during studies on the reaction of [Ir(mu-Cl)(coe)(2)}(2)] (coe = cis-cyclooctene) with tri-iso-propylphosphane in diethyl ether under dinitrogen atmosphere, have been analyzed by X-ray crystallography (monoclinic, P2(1)/c, Z = 2, a = 8.0855(9), b = 8.896(3), c = 16.539(3) angstrom; beta = 93.124(11)degrees; V = 1187.9(4); T = 200(2) K). In the course of these studies under an atmosphere of dinitrogen or argon, the formation of a variety of phosphorus-containing compounds was indicated using P-31{H-1} NMR spectroscopy.

引用

页码：1241 / 1243

页数：3

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