A Dimetallic Aminonitrone Nickel(II) Complex: Further Insights into Metal-Mediated Nucleophilic Activation of Amidoximes

被引：2

作者：

Bolotin, Dmitrii S. ^{[1
]}

Bikbaeva, Zarina M. ^{[1
]}

Novikov, Alexander S. ^{[1
]}

Suslonov, Vitalii V. ^{[2
]}

Bokach, Nadezhda A. ^{[1
]}

机构：

[1] St Petersburg State Univ, Inst Chem, Univ Skaya Nab 7-9, St Petersburg, Russia

[2] St Petersburg State Univ, Ctr Xray Diffract Studies, Univ Pr 26, St Petersburg, Russia

来源：

CHEMISTRYSELECT | 2017年 / 2卷 / 30期

基金：

俄罗斯科学基金会;

关键词：

amidoxime; aminonitrone; nitrone; nucleophilic activation; transition metal; LIGANDS; URANYL; COORDINATION; 1,2,4-OXADIAZOLES; ACETAMIDOXIME; GENERATION; CHEMISTRY; ADSORBENT; OXIMES; IONS;

D O I：

10.1002/slct.201702232

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of NiCl2 center dot 2H(2)O with acetamidoxime (MeC(NH2)=NOH) in the presence of PhCN in MeOH gave the cationic dimetallic complex [1]Cl-4, bearing bridging O-coordinated aminonitrone and chelating imidoylamidoxime ligands, derived from amidoxime-PhCN coupling. The experimental data and theoretical calculations (M06/MDF10(Ni) and 6-31G*(other atoms) indicated that the aminonitrone form of amidoxime was stabilized only as a (2)-O-bridging ligand, whereas N-oxime-coordination was preferred rather than O-coordination for monodentate-coordinated amidoximes.

引用

页码：9674 / 9678

页数：5

共 13 条

[11] ACTIVATION OF CARBON-DIOXIDE AT TRANSITION-METAL CENTERS - NICKEL(II) HETEROCYCLES FROM CARBON-DIOXIDE AND AZAOLEFINS AT THE ELECTRON-RICH NICKEL(0) COMPLEX MOIETY
WALTHER, D
DINJUS, E
SIELER, J
KAISER, J
LINDQVIST, O
ANDERSON, L
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 240 (03) : 289 - 297
[12] Metal-protein complex-mediated transport and delivery of Ni2+ to TCR/MHC contact sites in nickel-specific human T cell activation
Thierse, HJ
Moulon, C
Allespach, Y
Zimmermann, B
Doetze, A
Kuppig, S
Wild, D
Herberg, F
Weltzien, HU
JOURNAL OF IMMUNOLOGY, 2004, 172 (03): : 1926 - 1934
[13] A novel example of metal-mediated aromatic thiolation in a ruthenium complex. Crystal structure of Ru-II(SC6H4N=NC6H4N)2
Santra, BK
Thakur, GA
Ghosh, P
Pramanik, A
Lahiri, GK
INORGANIC CHEMISTRY, 1996, 35 (10) : 3050 - 3052

← 1 2 →