Mechanochemical Exfoliation of 2D Crystals in Deep Eutectic Solvents

被引：57
|
作者：
Abdelkader, A. M. [1 ,2 ]
Kinloch, I. A. [2 ,3 ]
机构：
[1] Univ Manchester, Sch Phys & Astron, Oxford Rd, Manchester M13 9LP, Lancs, England
[2] Univ Manchester, NGI, Booth St East, Manchester M13 9Q, Lancs, England
[3] Univ Manchester, Sch Mat, Oxford Rd, Manchester M13 9LP, Lancs, England
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2016年 / 4卷 / 08期
基金：
英国工程与自然科学研究理事会;
关键词：
Graphene; 2D materials; Mechanochemical; Deep eutectic solvents; TRANSITION-METAL DICHALCOGENIDES; CHEMICAL-VAPOR-DEPOSITION; FEW-LAYER GRAPHENE; ELECTROCHEMICAL EXFOLIATION; RAMAN-SPECTROSCOPY; CALCIOTHERMIC REDUCTION; ATMOSPHERIC-PRESSURE; BORON-NITRIDE; HIGH-QUALITY; GRAPHITE;
D O I：
10.1021/acssuschemeng.6b01195
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report a method for the large-scale production of 2D materials through the mechanochemical exfoliation of graphite or other layered compounds in deep eutectic solvents. The exfoliation process is based on the double intercalation of Li+ and Et4N+ ions within the layered crystals using the shear forces in the milling chamber as the driving force. The produced materials composed in majority of few-layer, large diameter flakes. The extent of exfoliation was found to be strongly dependent upon the energy input from the milling process, expressed in terms of the milling duration and the rotation speed.
引用
收藏
页码：4465 / 4472
页数：8
相关论文
共 50 条
  • [31] Computational Study of Molecular Interactions in ZnCl2(urea)2 Crystals as Precursors for Deep Eutectic Solvents
    Malinowski, Adrian
    Smiechowski, Maciej
    CRYSTALS, 2024, 14 (07)
  • [32] CO2 Valorization in Deep Eutectic Solvents
    Guo, Zhenbo
    Zhang, Zhicheng
    Huang, Yuchen
    Lin, Tianxing
    Guo, Yixin
    He, Liang-Nian
    Liu, Tianfei
    CHEMSUSCHEM, 2024, 17 (18)
  • [33] Exfoliation mechanisms of 2D materials and their applications
    Islam, Md Akibul
    Serles, Peter
    Kumral, Boran
    Demingos, Pedro Guerra
    Qureshi, Tanvir
    Meiyazhagan, AshokKumar
    Puthirath, Anand B.
    Abdullah, Mohammad Sayem Bin
    Faysal, Syed Rafat
    Ajayan, Pulickel M.
    Panesar, Daman
    Singh, Chandra Veer
    Filleter, Tobin
    APPLIED PHYSICS REVIEWS, 2022, 9 (04)
  • [34] Friction and mechanochemical reactivity of 2D nanomaterials
    Batteas, James
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
  • [35] Improving Whole-Cell Biocatalysis by Addition of Deep Eutectic Solvents and Natural Deep Eutectic Solvents
    Yang, Tao-Xiang
    Zhao, Li-Qing
    Wang, Juan
    Song, Guo-Li
    Liu, Hai-Min
    Cheng, Hui
    Yang, Zhen
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2017, 5 (07): : 5713 - 5722
  • [36] Advances in Deep Eutectic Solvents: New Green Solvents
    Ren, Shuhang
    Mu, Tiancheng
    Wu, Weize
    PROCESSES, 2023, 11 (07)
  • [37] Deep eutectic solvents as green solvents for materials preparation
    Yu, Dongkun
    Jiang, Depeng
    Xue, Zhimin
    Mu, Tiancheng
    GREEN CHEMISTRY, 2024, 26 (13) : 7478 - 7507
  • [38] Deep Eutectic Solvents: Green Solvents for Separation Applications
    Hou Yucui
    Yao Congfei
    Wu Weize
    ACTA PHYSICO-CHIMICA SINICA, 2018, 34 (08) : 873 - 885
  • [39] Green and sustainable solvents of the future: Deep eutectic solvents
    Prabhune, Aditi
    Dey, Ranjan
    JOURNAL OF MOLECULAR LIQUIDS, 2023, 379
  • [40] Deep insights into the exfoliation properties of MAX to MXenes and the hydrogen evolution performances of 2D MXenes
    Cheng, Yuwen
    Wang, Lijuan
    Song, Yan
    Zhang, Yumin
    JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (26) : 15862 - 15870
12345