4-(2,4-Dichlorophenyl)-5,5-dimethyl-2-(3-silatranylpropylmino)-1,3,2-dioxaphosphorinane 2-oxide

被引:1
|
作者
Liu, Zhe-Rong [1 ]
Tan, Xiao-Jing [1 ]
Wang, De-Jian [1 ]
Wang, Yan [1 ]
机构
[1] Hubei Univ Nationalities, Sch Chem & Environm Engn, Enshi 445000, Hubei, Peoples R China
关键词
BIOLOGICAL-ACTIVITIES;
D O I
10.1107/S1600536811044928
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C(20)H(31)Cl(2)N(2)O(6)PSi, the dioxaphosphorinane ring adopts a cis conformation. The silatrane fragment forms a cage-like structure in which there exists an intramolecular Si-N donor-acceptor bond. In the crystal, centrosymmetrically related molecules are linked by pairs of N-H center dot center dot center dot O hydrogen bonds into inversion dimers, generating rings with graph-set motif R(2)(2)(8). The dimers are further connected into ribbons parallel to the a axis by intermolecular C-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码:O3279 / U495
页数:12
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