2-arylazo-1-vinylpyrroles: Free-radical polymerization and copolymerization

被引：14

作者：

Trofimov, B. A. ^{[1
]}

Markova, M. V. ^{[1
]}

Morozova, L. V. ^{[1
]}

Shmidt, E. Yu. ^{[1
]}

Senotrusova, E. Yu. ^{[1
]}

Myachina, G. F. ^{[1
]}

Myachin, Yu. A. ^{[1
]}

Vakul'skaya, T. I. ^{[1
]}

Mikhaleva, A. I. ^{[1
]}

机构：

[1] Russian Acad Sci, Favorsky Inst Chem, Siberian Branch, Irkutsk 664033, Russia

来源：

POLYMER SCIENCE SERIES B | 2007年 / 49卷 / 11-12期

关键词：

D O I：

10.1134/S1560090407110061

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

2-Arylazo-1-vinylpyrroles (a new group of azo dyes of the pyrrole series) are polymerized under heating (80 C) without initiators and in the presence of AIBN to form intensely colored paramagnetic and conducting polymers with a yield of 92%. By the example of the thermal copolymerization with 1-vinylpyrrolidone, it has been shown that 2-arylazo-1-vinylpyrroles may simultaneously play the roles of initiators and comonomers.

引用

页码：292 / 296

页数：5

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