Iodination of organic substrates with halide salts and H2O2 using an organotelluride catalyst

被引:0
|
作者
Higgs, DE [1 ]
Nelen, MI [1 ]
Detty, MR [1 ]
机构
[1] SUNY Buffalo, Dept Chem, Div Med Chem, Buffalo, NY 14260 USA
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D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Organotelluride 1 is a water-soluble catalyst for the oxidation of iodide with hydrogen peroxide in pH 6 phosphate buffer. In two-phase systems, organic substrates are efficiently iodinated using 0.8 mol % of catalyst. Water-soluble substrates are iodinated without an organic cosolvent.
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页码:349 / 352
页数:4
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