Dehydration of fructose into 5-hydroxymethylfurfural in acidic ionic liquids

被引：52
|
作者：
Tao, Furong [1 ,2 ]
Song, Huanling [1 ]
Chou, Lingjun [1 ]
机构：
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
来源：
RSC ADVANCES | 2011年 / 1卷 / 04期
关键词：
HETEROGENEOUS ZIRCONIUM; SUBCRITICAL WATER; CATALYSTS; CONVERSION; GLUCOSE; 5-HYDROXYMETHYL-2-FURALDEHYDE; SUBSTANCES; SYSTEM; SUGARS;
D O I：
10.1039/c1ra00088h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple and effective process for the dehydration of fructose into 5-hydroxymethylfurfural (HMF) using ionic liquid 1-(4-sulfonic acid) butyl-3-methylimidazolium hydrogen sulfate (IL-1) as the catalyst was developed. High fructose conversion of 100% with HMF yield of 94.6% was obtained at 120 degrees C for 180 min reaction time in water-4-methyl-2-pentanone (MIBK) biphase system. Generally, the increase of water content had a negative effect on the reaction, the HMF selectivity decreased as the excessive elevation of temperature and prolonging of time, which suggested the decomposition of HMF. The ionic liquid IL-1 could be recycled and exhibited constant activity for six successful runs. This paper provided a new strategy for HMF production from fructose.
引用
下载
收藏
页码：672 / 676
页数：5
相关论文
共 50 条
  • [41] Dehydration of fructose to 5-hydroxymethylfurfural in sub- and supercritical acetone
    Bicker, M
    Hirth, J
    Vogel, H
    GREEN CHEMISTRY, 2003, 5 (02) : 280 - 284
  • [42] The Effect of Imidazolium Ionic Liquid on the Dehydration of Fructose to 5-Hydroxymethylfurfural, and a Room Temperature Catalytic System
    Lai, Linke
    Zhang, Yugen
    CHEMSUSCHEM, 2010, 3 (11) : 1257 - 1259
  • [43] Sustainable production of 5-hydroxymethylfurfural from fructose and inulin using active and stable acidic ionic liquids as homogeneous and heterogeneous catalysts
    Leticia, J. Mendez
    Alicia, Canepa
    Gustavo, P. Romanelli
    Monica, L. Casella
    Lick, Ileana D.
    SUSTAINABLE CHEMISTRY AND PHARMACY, 2024, 39
  • [44] Efficient catalytic dehydration of fructose into 5-hydroxymethylfurfural by carbon dioxide
    Wang, Chengqian
    Zhao, Caiyi
    Zhang, Long
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2022, 135 (04) : 1957 - 1970
  • [45] Facile catalytic dehydration of fructose to 5-hydroxymethylfurfural by Niobium pentachloride
    Mittal, Neha
    Nisola, Grace M.
    Chung, Wook-Jin
    TETRAHEDRON LETTERS, 2012, 53 (25) : 3149 - 3155
  • [46] Efficient Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Heteropolyacid Salts
    Song, Yanlei
    Wang, Xincheng
    Qu, Yongshui
    Huang, Chongpin
    Li, Yingxia
    Chen, Biaohua
    CATALYSTS, 2016, 6 (04)
  • [47] Sulfonated polyaniline as a solid organocatalyst for dehydration of fructose into 5-hydroxymethylfurfural
    Dai, Jinhang
    Zhu, Liangfang
    Tang, Dianyong
    Fu, Xing
    Tang, Jinqiang
    Guo, Xiawei
    Hu, Changwei
    GREEN CHEMISTRY, 2017, 19 (08) : 1932 - 1939
  • [48] Triazaheterocyclic compound as an efficient catalyst for dehydration of fructose into 5-hydroxymethylfurfural
    Huang, Zhen
    Pan, Yuanjia
    Chao, Yimin
    Shen, Wei
    Wang, Changchun
    Xu, Hualong
    RSC ADVANCES, 2014, 4 (26): : 13434 - 13437
  • [49] DFT study of fructose dehydration to 5-hydroxymethylfurfural catalyzed by imidazolium-based ionic liquid
    Li, Jingjing
    Yang, Yiying
    Zhang, Dongju
    CHEMICAL PHYSICS LETTERS, 2019, 723 : 175 - 181
  • [50] Theoretical study on conversion of fructose to 5-hydroxymethylfurfural in acidic media
    Nie, Xiaowa
    Liu, Xin
    Liu, Min
    Song, Chunshan
    Guo, Xinwen
    Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section), 2010, 26 (01): : 73 - 81
12345