Designer μ-oxo-bridged hypervalent iodine(III) organocatalysts for greener oxidations

被引:79
|
作者
Dohi, Toshifumi [1 ,2 ]
Takenaga, Naoko [2 ]
Fukushima, Kei-ichiro [1 ]
Uchiyama, Teruyoshi [1 ]
Kato, Daishi [1 ]
Shiro, Motoo [3 ]
Fujioka, Hiromichi [2 ]
Kita, Yasuyuki [1 ]
机构
[1] Ritsumeikan Univ, Coll Pharmaceut Sci, Shiga 5258577, Japan
[2] Osaka Univ, Grad Sch Pharmaceut Sci, Suita, Osaka 5650871, Japan
[3] Rigaku Corp, Tokyo 1968666, Japan
基金
日本学术振兴会;
关键词
M-CHLOROPERBENZOIC ACID; BIARYL COUPLING REACTION; TERMINAL OXIDANT; KETONES; CYCLIZATION; PHENOLS; REAGENT; IONS;
D O I
10.1039/c0cc03213a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The in situ generated mu-oxo-bridged reactive hypervalent iodine(III) species 1 or their analogues are introduced as more efficient organocatalysts for the catalytic strategy for realizing practical and greener oxidations.
引用
收藏
页码:7697 / 7699
页数:3
相关论文
共 50 条
  • [41] Study of antiferromagnetic phenomenon for oxo-bridged iron (III) dimers in model molecules of methemerythrin
    Kuang, XY
    Gou, QQ
    Zhou, KW
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2003, 64 (03) : 465 - 470
  • [42] Crystal structure and computational study of an oxo-bridged bis-titanium(III) complex
    Bloomfield, Hannah R.
    Hollett, Joshua W.
    Ritch, Jamie S.
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2021, 77 : 391 - +
  • [43] STRONGLY COUPLED, OXO-BRIDGED IRON (III) COMPLEXES MAGNETICALLY PERTURBED MOSSBAUER SPECTRA
    REIFF, WM
    JOURNAL OF CHEMICAL PHYSICS, 1971, 54 (11): : 4718 - &
  • [44] ELECTROCHEMISTRY AND STABILITY STUDIES OF OXO-BRIDGED DINUCLEAR RUTHENIUM(III) COMPLEXES FOR WATER OXIDATION
    RAMARAJ, R
    KIRA, A
    KANEKO, M
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 : 3515 - 3524
  • [45] 3,3′-Diiodo-BINOL-Fused Maleimides as Chiral Hypervalent Iodine(III) Organocatalysts
    Brenet, Simon
    Berthiol, Florian
    Einhorn, Jacques
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 2013 (36) : 8094 - 8096
  • [46] Versatile hypervalent-iodine(III)-catalyzed oxidations with m-chloroperbenzoic acid as a cooxidant
    Dohi, T
    Maruyama, A
    Yoshimura, M
    Morimoto, K
    Tohma, H
    Kita, Y
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (38) : 6193 - 6196
  • [47] Synthesis and characterization of a new unsymmetrical μ-oxo-bridged iron(III) complex with triphenylarsine oxide ligands
    Ondrejkovicova, I
    Lis, T
    Mrozinski, J
    Vancova, V
    Melnik, M
    INORGANICA CHIMICA ACTA, 1998, 277 (01) : 127 - 129
  • [48] Mechanistic studies on the oxidation of pyruvic acid by an oxo-bridged diiron(III,III) complex in aqueous acidic media
    Mandal, Pulak Chandra
    Bhattacharyya, Jhimli
    Das, Suranjana
    Mukhopadhyay, Subrata
    Kirschenbaum, Louis J.
    POLYHEDRON, 2009, 28 (14) : 3162 - 3168
  • [49] Control of the catalytic oxidations mediated by an oxo-bridged non-heme diiron complex: role of additives and reaction conditions
    Tanase, S
    Foltz, C
    de Gelder, R
    Hage, R
    Bouwman, E
    Reedijk, J
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 225 (02) : 161 - 167
  • [50] Synthesis and characterization of novel oxo-bridged, trinuclear mixed-metal complexes of Cr(III) and Fe(III)
    Yazdanbakhsh, Mohammad
    Khosravi, Iman
    Tavakkoli, Haman
    JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2009, 74 (04) : 401 - 406