J-aggregates granting giant second-order NLO responses in self-assembled hybrid inorganic organic materials

被引:0
|
作者
Cariati, E
Ugo, R
Cariati, F
Roberto, D
Masciocchi, N
Galli, S
Sironi, A
机构
[1] Univ Milan, Dipartimento Chim Inorgan Met Organ & Analit, I-20133 Milan, Italy
[2] Univ Milan, Ctr CNR, CSSSCMTBSO, I-20133 Milan, Italy
[3] Univ Insubria, Dipartimento Sci Chim Fis & Matemat, I-22100 Como, Italy
[4] Univ Insubria, Dipartimento Chim Strutt & Sterochim Inorgan, I-22100 Como, Italy
关键词
D O I
10.1002/1521-4095(200111)13:223.0.CO;2-X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Huge second harmonic generation (SHG) activity is displayed by the new hybrid inorganic-organic material [DAMS*][Cu5I6]. Ab-initio XRPD structure determination explains this through the presence of cationic guest J-aggregates between Cu-defective anionic host CuI slabs. Thermal stability and thin-film suitability make the material technologically interesting.
引用
收藏
页码:1665 / 1668
页数:4
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