The Trifluoromethyl Sulfinyl and Oxathiyl Radicals

被引：14

作者：

Wu, Zhuang ^{[1
]}

Xu, Jian ^{[1
]}

Deng, Guohai ^{[1
]}

Chu, Xianxu ^{[1
]}

Sokolenko, Liubov ^{[2
]}

Trabelsi, Tarek ^{[3
]}

Francisco, Joseph S. ^{[4
]}

Eckhardt, Andre K. ^{[5
]}

Schreiner, Peter R. ^{[5
]}

Zeng, Xiaoqing ^{[1
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

[2] Natl Acad Sci Ukraine, Organofluorine Chem Dept, Inst Organ Chem, UA-9402660 Kiev, Ukraine

[3] Univ Nebraska Lincoln, Lincoln, NE 68526 USA

[4] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

[5] Justus Liebig Univ, Inst Organ Chem, Heinrich Buff Ring 17, D-35392 Giessen, Germany

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2018年 / 24卷 / 07期

基金：

中国国家自然科学基金;

关键词：

ab initio computations; IR spectroscopy; isomerization; radicals; sulfur; GAS-PHASE; PEROXYL RADICALS; THIYL RADICALS; CENTER-DOT; HSO; ISOMERS; CH3(O)S-CENTER-DOT; DECOMPOSITION; STABILITY; CHEMISTRY;

D O I：

10.1002/chem.201705142

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two hitherto unreported sulfur-centered radicals CF3SO center dot and CF3OS center dot were generated in the gas phase through high-vacuum flash pyrolyses of sulfoxide CF3S(O)X (X=CF3, Cl, PhO) precursors. The CF3OS center dot molecule is the first experimental example that constitutes an oxathiyl radical. It was isolated and characterized by combining matrix-isolation IR and UV/Vis spectroscopy with quantum chemical computations up to the UCCSD(T)-F12/cc-pVTZ-F12 level of theory. Upon UV light irradiation (254 or 266nm), sulfinyl radical (CF3SO center dot) isomerizes to oxathiyl radical (CF3OS center dot) in cryogenic noble gas matrices (Ar and Ne). Natural population analyses at the BP86/def2-TZVPP//UCCSD(T)-F12/cc-pVTZ-F12 level suggest that the spin density in CF3OS center dot is mainly localized on the sulfur atom (0.86), whereas, in CF3SO center dot the spin density is almost equally distributed on the sulfur (0.55) and oxygen (0.43) atoms.

引用

页码：1505 / 1508

页数：4

共 50 条

[41] RATE CONSTANTS FOR INTERACTION OF TRIFLUOROMETHYL RADICALS WITH OXYGEN AND FLUORINE
ARUTYUNOV, VS
GORSHENEV, SI
CHAIKIN, AM
REACTION KINETICS AND CATALYSIS LETTERS, 1977, 6 (02): : 161 - 167
[42] RATE CONSTANTS OF REACTIONS OF TRIFLUOROMETHYL RADICALS WITH OXYGEN AND FLUORINE
TEITELBOIM, MA
VEDENEEV, VI
KINETICS AND CATALYSIS, 1985, 26 (06) : 1119 - 1123
[43] REACTIONS OF TRIFLUOROMETHYL RADICALS WITH IODINE AND NITRIC-OXIDE
AMPHLETT, JC
MACAULEY, LJ
CANADIAN JOURNAL OF CHEMISTRY, 1976, 54 (08) : 1234 - 1238
[44] HYDROGEN ABSTRACTION FROM AROMATIC ALDEHYDES BY TRIFLUOROMETHYL RADICALS
MAJER, JR
NAMAN, SAM
ROBB, JC
TRANSACTIONS OF THE FARADAY SOCIETY, 1969, 65 (564P): : 3295 - &
[45] ROLE OF TRIFLUOROMETHYL RADICALS IN RADIATION POLYMERIZATION OF GASEOUS TETRAFLUOROETHYLENE
COOPER, R
ROY, CR
AUSTRALIAN JOURNAL OF CHEMISTRY, 1970, 23 (05) : 939 - &
[46] TRIFLUOROMETHYL AND OTHER RADICALS IN IRRADIATED SINGLE CRYSTALS OF TRIFLUOROACETAMIDE
ROGERS, MT
KISPERT, LD
JOURNAL OF CHEMICAL PHYSICS, 1967, 46 (08): : 3193 - &
[47] ARRHENIUS PARAMETERS FOR THE REACTION OF TRIFLUOROMETHYL RADICALS WITH CYANOGEN CHLORIDE
COSA, F
OEXLER, EV
STARICCO, EH
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1981, 77 : 253 - 260
[48] HYDROGEN ABSTRACTION FROM DIMETHYL SULFIDE BY TRIFLUOROMETHYL RADICALS
ARTHUR, NL
YEO, KS
AUSTRALIAN JOURNAL OF CHEMISTRY, 1979, 32 (09) : 2077 - 2078
[49] REACTIONS OF TRIFLUOROMETHYL RADICALS WITH MONOSILANE AND MONOSILANE-D
JAKUBOWS.E
SANDHU, HS
GUNNING, HE
STRAUSZ, OP
JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (08): : 4242 - &
[50] REACTIONS OF TRIFLUOROMETHYL RADICALS WITH BROMINE CHLORINE AND HYDROGEN CHLORIDE
AMPHLETT, JC
WHITTLE, E
TRANSACTIONS OF THE FARADAY SOCIETY, 1966, 62 (522P): : 1662 - &

← 1 2 3 4 5 →