Nonlinear dynamics in frontal polymerization

被引:0
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作者
Pojman, JA [1 ]
Popwell, S
Fortenberry, DI
Volpert, VA
Volpert, VA
机构
[1] Univ So Mississippi, Dept Chem & Biochem, Hattiesburg, MS 39406 USA
[2] Mississippi Univ Women, Columbus, MS 39701 USA
[3] Univ Lyon 1, MAPLY, UMR 5585, F-69622 Villeurbanne, France
[4] Northwestern Univ, Dept Engn Sci & Appl Math, Evanston, IL 60208 USA
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Thermal frontal polymerization is a mode of converting monomer into polymer via a localized exothermic reaction zone that propagates through the coupling of thermal diffusion and the Arrhenius reaction kinetics of an exothermic polymerization. We review the range of nonlinear phenomena that have been observed in frontal polymerization systems and report new results on the role of gravity in spin modes and the development of spherically-propagating fronts.
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页码:106 / 120
页数:15
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