The first total synthesis of the antimicrobial sesquiterpenes (±)-enokipodins A and B

被引：25
|
作者：
Srikrishna, A [1 ]
Rao, MS [1 ]
机构：
[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India
来源：
SYNLETT | 2004年 / 02期
关键词：
sesquiterpenes; enokipodins A and B; ring-closing metathesis; Claisen rearrangement;
D O I：
10.1055/s-2003-45003
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Efficient first total synthesis of antimicrobial sesquiterpenes enokipodins A and B (1 and 2, respectively) and formal total synthesis of cuparene-1,4-diol (5) and cuparene-1,4-quinone (7) have been accomplished starting from 2,5-dimethoxy-4-methylacetophenone employing Claisen rearrangement and ring-closing metathesis reaction as key steps.
引用
收藏
页码：374 / 376
页数：3
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