Ligand-Free Palladium-Catalyzed C-S Coupling Reactions Using Water as Solvent and Microwaves

被引：17
|
作者：
Velmathi, Sivan [1 ,2 ]
Vijayaraghavan, Reena [1 ]
Amarendar, Ch [1 ]
Pal, Ravindra P. [2 ]
Vinu, Ajayan [2 ]
机构：
[1] Natl Inst Technol, Dept Chem, Organ & Polymer Synth Lab, Tiruchirappalli 620015, Tamil Nadu, India
[2] Natl Inst Mat Sci, World Premier Int WPI Res Initiat, Int Ctr Mat Nanoarchitecton, Tsukuba, Ibaraki 3050044, Japan
来源：
SYNLETT | 2010年 / 18期
关键词：
C-S coupling; aryl halides; thiols; microwave; palladium acetate; ADDITIVE-FREE CONDITIONS; ARYL HALIDES; NUCLEOPHILIC-SUBSTITUTION; EFFICIENT; THIOLS; ARYLATION; SULFIDES; IODIDES; CARBON; MILD;
D O I：
10.1055/s-0030-1258815
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Herein we demonstrate for the first time a rapid and efficient method for the synthesis of aryl sulfides by the direct substitution reaction of aromatic thiols with aryl halides using water as solvent under microwave irradiation. This procedure offers a high yield in shorter reaction time as compared to conventional methods.
引用
收藏
页码：2733 / 2736
页数：4
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