Rhodium-catalyzed [5+2] cycloaddition reactions in water

被引：44
|
作者：
Wender, PA [1 ]
Love, JA [1 ]
Williams, TJ [1 ]
机构：
[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
来源：
SYNLETT | 2003年 / 09期
关键词：
water-soluble catalyst; biphasic reactions; cycloaddition; medium-sized rings; rhodium;
D O I：
10.1055/s-2003-40357
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new water-soluble rhodium catalyst is reported along with its ability to effect [5+2] cycloaddition reactions in water. This water-soluble catalyst is recyclable, is readily separated from the organic product, and allows one to avoid or minimize the use of organic solvents, the major waste stream of most organic reactions.
引用
收藏
页码：1295 / 1298
页数：4
相关论文
共 50 条
  • [31] Rhodium-catalyzed [4+2+2] cycloaddition reactions for the synthesis of eight-membered ring compounds
    Canlas, Gino Martin R.
    Gilbertson, Scott R.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [32] Rhodium-catalyzed intermolecular [4+2] cycloaddition of unactivated substrates
    Murakami, M
    Ubukata, M
    Itami, K
    Ito, Y
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1998, 37 (16) : 2248 - 2250
  • [33] Mechanistic investigation of a rhodium-catalyzed [4+2] cycloaddition.
    Morehead, AT
    Kundu, K
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U130 - U130
  • [34] New rhodium-catalyzed amination reactions
    Trauthwein, H
    Tillack, A
    Beller, M
    CHEMICAL COMMUNICATIONS, 1999, (20) : 2029 - 2030
  • [35] Ruthenium and Rhodium-Catalyzed Carbonylation Reactions
    Wu, Xiao-Feng
    Neumann, Helfried
    CHEMCATCHEM, 2012, 4 (04) : 447 - 458
  • [36] Rhodium-Catalyzed Regio- and Stereoselective [2+2] Cycloaddition of Allenamides
    Zheng, Wei-Feng
    Bora, Pranjal Protim
    Sun, Gui-Jun
    Kang, Qiang
    ORGANIC LETTERS, 2016, 18 (15) : 3694 - 3697
  • [37] Rhodium-Catalyzed Atroposelective Click Cycloaddition of Azides and Alkynes
    Zeng, Linwei
    Li, Jiaming
    Cui, Sunliang
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (28)
  • [38] Rhodium-Catalyzed Linear Codimerization and Cycloaddition of Ketenes with Alkynes
    Kondo, Teruyuki
    Niimi, Masatsugu
    Yoshida, Yuki
    Wada, Kenji
    Mitsudo, Take-aki
    Kimura, Yu
    Toshimitsu, Akio
    MOLECULES, 2010, 15 (06) : 4189 - 4200
  • [39] Rhodium-catalyzed asymmetric [4+1] cycloaddition
    Murakami, M
    Itami, K
    Ito, Y
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (12) : 2950 - 2951
  • [40] Rhodium-catalyzed cycloaddition of alkylidenecyclopropanes under carbon monoxide
    Kim, Seyun
    Chung, Young Keun
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
12345