Kinetics and mechanism of electron transfer reactions: Oxidation of hypophosphorus acid by peroxodisulphate induced by irradiation with visible light in an aqueous solution containing tris(2,2'-bipyridine) ruthenium(II) ion

被引：0

作者：

Bansal, S. ^{[1
]}

Soni, N. K. ^{[1
]}

Khandelwal, C. L. ^{[1
]}

Sharma, P. D. ^{[1
]}

机构：

[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India

来源：

OXIDATION COMMUNICATIONS | 2007年 / 30卷 / 04期

关键词：

electron transfer reaction; oxidation; hypophosphorus acid; irradiation; peroxodisulphate;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of oxidation of hypophosphorous acid by peroxodisulphate in the presence of photocatalyst [Ru(bipy)(3)(2+)] induced by irradiation with visible light indicates the following rate law: [GRAPHICS] where k(q) and k(0) are the quenching and excitation rate constants, respectively.

引用

页码：772 / 777

页数：6

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