Syntheses and characterization of two metal-organic frameworks with in situ-generated 5-(4-pyridyl)tetrazolate and azide

被引：13
|
作者：
Yang, Yu-Ting [1 ]
Zhao, Fang-Hua [1 ]
Che, Yun-Xia [1 ]
Zheng, Ji-Min [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 12期
基金：
中国国家自然科学基金;
关键词：
Hydro(solvo)thermal synthesis; In situ; Azide; (3,5,6)-connected; Luminescence; COORDINATION POLYMERS; 5-SUBSTITUTED; 1H-TETRAZOLES; ADSORPTION; COMPLEXES; ROUTE;
D O I：
10.1016/j.inoche.2011.08.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two novel metal-organic frameworks of [M-3(ptz)(2)(N-3)(4)(H2O)(2)] (M = Zn(1), Cd(2)) (Ptz = 5-(4-pyridyl)tetrazolate) have been prepared hydro(solvo)thermally by reactions of 4-cyanopyridine and excess NaN3 in the presence of zinc and cadmium chloride, respectively. The overall structure motif of complexes 1 and 2 show pillared layered frameworks and feature an unprecedented 3-nodal network with (3,5,6)-connectivity. The layer is of particular interest as it is constructed by mu(1,1)-N-3(-) and mu(1,1,3)-N-3(-) bridging modes, simultaneously. Furthermore, the solid fluorescent properties and TGA were studied. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：1855 / 1859
页数：5
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