The effect of manganese on the structural and surface properties of nanocrystalline cobalt catalyst for ammonia synthesis

被引:1
|
作者
Lendzion-Bielun, Zofia [1 ]
机构
[1] W Pomeranian Univ Technol, Inst Inorgan Chem Technol & Environm Engn, PL-70322 Szczecin, Poland
来源
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY | 2012年 / 10卷 / 02期
关键词
Ammonia synthesis; Cobalt catalyst; Activity; Thermal resistance; NICKEL ALLOY CATALYSTS; FUSED IRON CATALYST; CARBON; 853-K; MODEL;
D O I
10.2478/s11532-011-0147-y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Based on the active surface model of the iron catalyst for ammonia synthesis, the assumptions which led to obtaining the cobalt catalyst for ammonia synthesis were described. The incorporation into the system small amounts of manganese, an element which binds oxygen stronger than cobalt, has influence the development of the catalyst's specific surface area. The activity of manganese modified catalysts is higher than that of cobalt catalyst without manganese addition. The obtained catalysts were characterized with the following methods: ICP-OES, XRD, BET
引用
收藏
页码:327 / 331
页数:5
相关论文
共 50 条
  • [31] Temperature effect on structural transformations in nanocrystalline cobalt films
    Frolov, GI
    Zhigalov, VS
    Mal'tsev, VK
    PHYSICS OF THE SOLID STATE, 2000, 42 (02) : 334 - 336
  • [32] Temperature effect on structural transformations in nanocrystalline cobalt films
    G. I. Frolov
    V. S. Zhigalov
    V. K. Mal’tsev
    Physics of the Solid State, 2000, 42 : 334 - 336
  • [33] Synthesis and structural evaluation of manganese doped cobalt oxides
    Thuli, Alexis
    Morey, Aimee
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [34] Fischer-Tropsch synthesis: Effect of ammonia impurities in syngas feed over cobalt catalyst
    Pendyala, Venkat Ramana Rao
    Gnanamani, Muthu Kumaran
    Ma, Wenping
    Jacobs, Gary
    Shafer, Wilson D.
    Davis, Burtron H.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [35] Structural properties of gahnite doped with cobalt, manganese or titanium
    Grzeta, Biserka
    Popovic, Jasminka
    Vrankic, Martina
    Tkalcec, Emilija
    Kurajica, Stanislav
    Rakvin, Boris
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C578 - C578
  • [36] Surface and catalytic properties of potassium-modified cobalt molybdenum catalysts for ammonia synthesis
    Moszynski, Dariusz
    Jedrzejewski, Roman
    Ziebro, Janusz
    Arabczyk, Walerian
    APPLIED SURFACE SCIENCE, 2010, 256 (17) : 5581 - 5584
  • [37] Surface properties of wustite based iron-cobalt catalysts for ammonia synthesis reaction
    Lendzion-Bieluń, Zofia
    Jurkowski, Artur
    Catalysis Communications, 2020, 136
  • [38] Surface properties of wustite based iron-cobalt catalysts for ammonia synthesis reaction
    Lendzion-Bielun, Zofia
    Jurkowski, Artur
    CATALYSIS COMMUNICATIONS, 2020, 136
  • [39] Study of cobalt doping on structural and luminescence properties of nanocrystalline ZnO
    Husain, Shahid
    Alkhtaby, Lila. A.
    Bhat, Irshad
    Giorgetti, Emilia
    Zoppi, Angela
    Miranda, Maurizio Muniz
    JOURNAL OF LUMINESCENCE, 2014, 154 : 430 - 436
  • [40] Structural and magnetic properties of nanocrystalline stannic substituted cobalt ferrite
    Abbas, Y. M.
    Mansour, S. A.
    Ibrahim, M. H.
    Ali, Shehab. E.
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2012, 324 (18) : 2781 - 2787