Poly[bis(μ2-5-n-butyltetrazolato-k2N1:N4)zinc(II)]

被引：2
|
作者：
Tong, Xiao-Lan [1 ]
Liu, Hao [1 ]
Yu, Qun [1 ]
Li, Jian-Rong [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S160053680706518X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [Zn(C5H9N4)(2)](n), the Zn-II center is coordinated by four N atoms of different tetrazolate ligands with a slightly distorted tetrahedral geometry [Zn-N distances and N-Zn-N angles are in the ranges 1.991 (2)-2.007 (2) angstrom and 104.22 (8)-116.13 (8)degrees, respectively]. Each ligand links two Zn-II atoms through its 1-and 4-position tetrazole N atoms, forming a single, fully connected three-dimensional framework with a diamond-like topology. In the crystal structure, the Zn center dot center dot center dot Zn separations across each tetrazole unit are 6.115 (2) and 6.134 (2) angstrom and the Zn center dot center dot center dot Zn center dot center dot center dot Zn angles are in the range 107.77 (8)-116.83 (8)degrees.
引用
收藏
页码：M132 / U1276
页数：10
相关论文
共 50 条
  • [21] Poly[bis(μ2-pyrimidine-κ2N:N′)bis(selenocyanato-κN)zinc]
    Boeckmann, Jan
    Reinert, Thorben
    Naether, Christian
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M948 - U1189
  • [22] catena-Poly[[[bis[2,2′-(propane-1,3-diyldithio)bis(1,3,4-thiadiazole)-κN4]copper(II)]-bis[μ-2,2′-(propane-1,3-diyldithio)bis(1,3,4-thiadiazole)-κ2N4:N4′]] bis(perchlorate)]
    Qin, Jian-Hua
    Wang, Jian-Ge
    Hu, Pu-Zhou
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M349 - U1042
  • [23] catena-poly[[diiodocadmium(II)]-μ-1,4-bis-(1,2,4-triazol-1-ylmethyl) benzene-κ2N4: N4′]
    Niu, YY
    Zhang, HL
    Hou, HW
    Ng, SW
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M2536 - M2537
  • [24] Poly[[tris[μ-2,2′-(butane-1,4-diyldithio)bis(1,3,4-thiadiazole)-κ2N4:N4′]copper(II)]bis(perchlorate)]
    Hu, Pu-Zhou
    Qin, Jian-Hua
    Wang, Jian-Ge
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M307 - U731
  • [25] μ-1,2-di-4-pyridylethane-κ2N: N′-bis[bis(N,N-diisopropyldithiocarbamato-κ2S,S′)zinc(II)]
    Avila, Vanessa
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M680 - U593
  • [26] (μ-4,4′-Bipyridine-κ2N:N′)bis[bis(N,N-dimethyldithiocarbamato-κ2S,S′)zinc(II)]
    Zha, Mei-Qin
    Li, Xing
    Bing, Yue
    Lu, Yue
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1465 - U1191
  • [27] Bis(2-aminopyrazine-κN4)dichloridozinc
    Gao, Shan
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1049 - U494
  • [28] cis-Bis(μ-50-phenyl-3-p-tolylpyrazolato-k2N:N′)-bis[(4,4′-dimethyl-2,2′-bipyridine-k2N,N′)palladium(II)] trans-bis(μ-5-phenyl-3-p-tolylpyrazolato-k2N:N′)bis[bis[(4,4′-dimethyl-2,2′-bipyridine-k2N,N′)-palladium(II)] tetrakis(tetrafluoridoborate)
    Huang, Hai-Ping
    Ma, Hong-Wei
    Li, Yi-Zhi
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M1089 - M1091
  • [29] Dinuclear zinc(II) complexes of N,N′-bis[2-(hydroxyphenyl)methyl]-N, N′-bis(2-pyridylmethyl)-1,n-alkanediamines
    Fenton, D.E. (d.fenton@sheffield.ac.uk), 2001, Wiley-VCH Verlag
  • [30] Dinuclear zinc(II) complexes of N,N′-bis[2-(hydroxyphenyl)methyl]-N,N′-bis(2-pyridylmethyl)-1,n-alkanediamines
    Adams, H
    Bradshaw, D
    Fenton, DE
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2001, (03) : 859 - 864
12345