Poly[bis(μ2-5-n-butyltetrazolato-k2N1:N4)zinc(II)]

被引：2
|
作者：
Tong, Xiao-Lan [1 ]
Liu, Hao [1 ]
Yu, Qun [1 ]
Li, Jian-Rong [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S160053680706518X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [Zn(C5H9N4)(2)](n), the Zn-II center is coordinated by four N atoms of different tetrazolate ligands with a slightly distorted tetrahedral geometry [Zn-N distances and N-Zn-N angles are in the ranges 1.991 (2)-2.007 (2) angstrom and 104.22 (8)-116.13 (8)degrees, respectively]. Each ligand links two Zn-II atoms through its 1-and 4-position tetrazole N atoms, forming a single, fully connected three-dimensional framework with a diamond-like topology. In the crystal structure, the Zn center dot center dot center dot Zn separations across each tetrazole unit are 6.115 (2) and 6.134 (2) angstrom and the Zn center dot center dot center dot Zn center dot center dot center dot Zn angles are in the range 107.77 (8)-116.83 (8)degrees.
引用
收藏
页码：M132 / U1276
页数：10
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