Iodine-catalyzed allylic alkylation of sulfonamides and carbamates with allylic alcohols at room temperature

被引：59

作者：

Wu, Wenhan ^{[1
]}

Rao, Weidong ^{[1
]}

Er, Ya Qin ^{[1
]}

Loh, Joanna Kejun ^{[1
]}

Poh, Chal Yuri ^{[1
]}

Chan, Philip Wai Hong ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Math & Phys Sci, Div Chem & Biol Chem, Singapore 637371, Singapore

来源：

TETRAHEDRON LETTERS | 2008年 / 49卷 / 16期

关键词：

D O I：

10.1016/j.tetlet.2008.02.079

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly efficient iodine-catalyzed allylic alkylation of a wide variety of sulfonamides and carbamates with allylic alcohols is reported herein. The reaction is operationally straightforward and proceeds under very mild conditions at room temperature in good to excellent yields (up to 99%). (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：2620 / 2624

页数：5

共 50 条

[31] Asymmetric Allylic Alkylation of -Ketoesters with Allylic Alcohols by a Nickel/Diphosphine Catalyst
Kita, Yusuke
Kavthe, Rahul D.
Oda, Hiroaki
Mashima, Kazushi
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (03) : 1098 - 1101
[32] Gold- and silver-catalyzed allylic alkylation of 1,3-dicarbonyl compounds with allylic alcohols
Kothandaraman, Prasath
Rao, Weidong
Zhang, Xiaoxiang
Chan, Philip Wai Hong
TETRAHEDRON, 2009, 65 (09) : 1833 - 1838
[33] ALLYLIC ALCOHOLS AS SUBSTRATES FOR THE PALLADIUM(0)-CATALYZED ALLYLIC SUBSTITUTION
STARY, I
STARA, IG
KOCOVSKY, P
TETRAHEDRON LETTERS, 1993, 34 (01) : 179 - 182
[34] ALKYLATION OF ALLYLIC DERIVATIVES .9. ON THE STEREOCHEMISTRY OF ALKYLATION OF ACYCLIC ALLYLIC ALCOHOLS BY THE MURAHASHI METHOD
GOERING, HL
TSENG, CC
JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (10): : 1597 - 1599
[35] Pd-Catalyzed Allylic Substitution of Azo-Ene Adducts Enables Net Allylic C-H Alkylation of Allylic Alcohols
Kuroda, Yusuke
Chiba, Takumi
Kawajiri, Moe
Takasu, Kiyosei
ORGANIC LETTERS, 2025, 27 (06) : 1517 - 1523
[36] Direct use of allylic alcohols and allylic amines in palladium-catalyzed allylic amination
Jing, Jiangyan
Huo, Xiaohong
Shen, Jiefeng
Fu, Jingke
Meng, Qinghua
Zhang, Wanbin
CHEMICAL COMMUNICATIONS, 2017, 53 (37) : 5151 - 5154
[37] Osmium-catalyzed allylic alkylation
Esteruelas, Miguel A.
Garcia-Yebra, Cristina
Olivan, Montserrat
Onate, Enrique
Valencia, Marta
ORGANOMETALLICS, 2008, 27 (19) : 4892 - 4902
[38] IRON-CATALYZED ALLYLIC ALKYLATION
LADOULIS, SJ
NICHOLAS, KM
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 285 (1-3) : C13 - C16
[39] PALLADIUM CATALYZED ALLYLIC ALKYLATION OF OLEFINS
HEGEDUS, LS
HAYASHI, T
DARLINGTON, WH
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (24) : 7747 - 7748
[40] PALLADIUM-CATALYZED ALLYLIC ALKYLATION OF ALLYLIC NITROCOMPOUNDS WITH STABILIZED CARBANIONS
ONO, N
HAMAMOTO, I
KAJI, A
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (08): : 1439 - 1443

← 1 2 3 4 5 →