Hydrogen-Bond-Assisted Reinforcement of Interlayer Connections in Zn2BO3X•H2O (X = Cl, Br): Two UV Nonlinear Optical Crystals with KBBF-Type Structure

被引：8

作者：

Song, Yunxia ^{[1
]}

Yang, Guangsai ^{[2
]}

Gong, Pifu ^{[3
]}

Luo, Min ^{[2
]}

Lin, Zheshuai ^{[3
]}

Ye, Ning ^{[2
]}

机构：

[1] Fujian Univ Technol, Coll Math & Phys, Fuzhou 350118, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Fujian, Peoples R China

[3] Chinese Acad Sci, Tech Inst Phys & Chem, Ctr Crystal Res & Dev, Beijing 100190, Peoples R China

来源：

INORGANIC CHEMISTRY | 2020年 / 59卷 / 11期

基金：

中国国家自然科学基金;

关键词：

ALKALINE BERYLLIUM BORATE; RB; MECHANISM; DESIGN;

D O I：

10.1021/acs.inorgchem.0c00874

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel zinc borate halides named Zn2BO3X center dot H2O (X = Cl, Br) were discovered through hydrothermal techniques. Both compounds are isomorphic and feature the layered structure similar to that of KBBF, consisting of the infinite planar [Zn2BO3X center dot OH2] (X = Cl, Br) layers. Compared with the weak ionic bond between adjacent layers in KBBF, the strong interaction of hydrogen bonds between layers in Zn2BO3X center dot H2O (X = Cl, Br) effectively enhances the interlayer force, contributing to eliminating the layering growth tendency. Optical measurements on these two NLO crystals revealed that they have a broad wavelength transparency window and a moderate NLO coefficient. Moreover, the theoretical calculations revealed that the linear and NLO properties primarily depended on the [BO3] and [ZnO3Cl/Br] groups in both crystals.

引用

页码：7789 / 7794

页数：6

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