Struvite Precipitation for Ammonia Nitrogen Removal in 7-Aminocephalosporanic Acid Wastewater

被引:31
|
作者
Li, Zaixing [1 ,2 ]
Ren, Xuguang [1 ]
Zuo, Jiane [2 ]
Liu, Yanfang [1 ]
Duan, Erhong [1 ]
Yang, Jingliang [1 ]
Chen, Ping [3 ]
Wang, Yongjun [3 ]
机构
[1] Hebei Univ Sci & Technol, Sch Environm Sci & Engn, Shijiazhuang 050018, Peoples R China
[2] Tsinghua Univ, Dept Environm Sci & Engn, Beijing 100084, Peoples R China
[3] N China Pharmaceut Co, Shijiazhuang 050015, Peoples R China
关键词
struvite; 7-aminocephalosporanic acid; wastewater; ammonia nitrogen; precipitation; CHEMICAL PRECIPITATION; LANDFILL LEACHATE; HIGH-STRENGTH; PHOSPHATE; RECOVERY; MAGNESIUM; CRYSTALLIZATION; PRETREATMENT; PHOSPHORUS; LIQUID;
D O I
10.3390/molecules17022126
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
7-Aminocephalosporanic acid wastewater usually contains high concentrations of ammonium (NH4+-N), which is known to inhibit nitrification during biological treatment processes. Chemical precipitation is a useful technology to remove ammonium from wastewater. In this paper, the removal of ammonium from 7-aminocephalosporanic acid wastewater was studied. The optimum pH, molar ratio, and various chemical compositions of magnesium ammonium phosphate (MAP) precipitation were investigated. The results indicated that ammonium in 7-aminocephalosporanic acid wastewater could be removed at an optimum pH of 9. The Mg2+:NH4+-N:PO43--P molar ratio was readily controlled at a ratio of 1:1:1.1 to both effectively remove ammonium and avoid creating a higher concentration of PO43--P in the effluent. MgCl2 center dot 6H(2)O + 85% H3PO4 was the most efficient combination for NH4+-N removal. Furthermore, the lowest concentration of the residual PO43--P was obtained with the same combination. Struvite precipitation could be considered an effective technology for the NH4+-N removal from the 7-aminocephalosporanic acid wastewater.
引用
收藏
页码:2126 / 2139
页数:14
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