Synthesis of heterodinuclear ruthenium-manganese complex having μ-benzylidene ligand

被引：2
|
作者：
Tanaka, Shin-ichi [1 ]
Komine, Nobuyuki [1 ]
Hirano, Masafumi [1 ]
Komiya, Sanshiro [1 ]
机构：
[1] Tokyo Univ Agr & Technol, Grad Sch Engn, Dept Appl Chem, Koganei, Tokyo 1848588, Japan
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 02期
关键词：
Heterodinuclear complex; Carbene; Ruthenium; Manganese; TRI-METAL COMPLEXES; RAY CRYSTAL-STRUCTURES; BETA-HYDROGEN ELIMINATION; PLATINUM-TUNGSTEN COMPOUNDS; BRIDGING CARBENE; CARBYNE LIGANDS; DI-METAL; SPECTROSCOPIC PROPERTIES; ORGANOMETALLIC COMPLEX; CO INSERTION;
D O I：
10.1016/j.jorganchem.2010.09.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new benzylidene-bridged heterodinuclear complex (Cy3P)(OC)(2)Ru(mu-CHPh)(mu-Cl)Mn(CO)(3)(PCy3) (1) was synthesized by metathesis reaction of RuCl2(PCy3)(2)(=CHPh) with Na+[Mn(CO)(5)](-). Highly congested structure hinders rotation of the phenyl substituent on the mu-carbene carbon, showing fluxionality in H-1 NMR. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：632 / 635
页数：4
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