Structure analysis of photo-induced triplet phenylnitrene using synchrotron radiation

被引：19

作者：

Kawano, M ^{[1
]}

Takayama, T

Uekusa, H

Ohashi, Y

Ozawa, Y

Matsubara, K

Imabayashi, H

Mitsumi, M

Toriumi, K

机构：

[1] Tokyo Inst Technol, Dept Chem & Mat Sci, Meguro Ku, Tokyo 1528551, Japan

[2] Japan Sci & Technol Corp, CREST, Kawaguchi 3320012, Japan

[3] Himeji Inst Technol, Dept Mat Sci, Himeji, Hyogo 6781297, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 10期

关键词：

D O I：

10.1246/cl.2003.922

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of [(PhCH2)(2)NH2](+)[m-C6H4(N-3)-(COO)](-) before and after UV-irradiation were analyzed at 25 K by using an X-ray vacuum camera set up at the synchrotron laboratory (SPring-8). The C-N (nitrene) bond distance in the triplet state of the photo-induced m-carboxyphenylnitrene is determined to be 1.34(4) Angstrom.

引用

页码：922 / 923

页数：2

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