New thiazolothiazole derivatives as fluorescent chemosensors for Cr3+ and Al3+

被引:134
|
作者
Jung, Ji Young [2 ]
Han, Su Jung [1 ]
Chun, Jihyun [1 ]
Lee, Chongmok [1 ]
Yoon, Juyoung [1 ,2 ]
机构
[1] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea
[2] Ewha Womans Univ, Dept Bioinspired Sci WCU, Seoul 120750, South Korea
基金
新加坡国家研究基金会;
关键词
Fluorescent chemosensors; Thiazolothiazole; Sensing chromium ion; Sensing Aluminium ion; Ratiometric sensor; Fluorescent probe; SELECTIVE DETECTION; RECENT PROGRESS; COLORIMETRIC CHEMOSENSORS; PYRENE; SENSOR; CHEMODOSIMETERS; PROBES;
D O I
10.1016/j.dyepig.2012.02.005
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Two new 2,5-diarylthiazolo[5,4-d]thiazole derivatives bearing ethylene oxide moieties were synthesized. Their photophysical and electrochemical properties as well as binding properties towards various metal ions were examined. Thiazole derivative 1 showed large fluorescent enhancements with Cr3+ and Al3+. On the other hand, thiazole derivative 2 displayed a selective fluorescent change with Cr3+ among the metal ions examined. As far as we are aware of, these are the first examples of thiazolothiazole derivatives as fluorescent chemosensors for metal ions. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:423 / 426
页数:4
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