Synthesis of Continuous Mesoporous Ga-Doped Titania Films with Anatase Crystallized Framework

被引:14
|
作者
Oveisi, Hamid [1 ,2 ]
Beitollahi, Ali [2 ]
Jiang, Xiangfen [1 ,3 ]
Sato, Keisuke [1 ]
Nemoto, Yoshihiro [1 ]
Fukata, Naoki [1 ]
Yamauchi, Yusuke [1 ,3 ,4 ]
机构
[1] Natl Inst Mat Sci NIMS, World Premier Int WPI Res Ctr Mat Nanoarchitecton, Tsukuba, Ibaraki 3050044, Japan
[2] Iran Univ Sci & Technol IUST, Ctr Excellence Adv Mat & Proc, Sch Met & Mat Engn, Tehran, Iran
[3] Waseda Univ, Fac Sci & Engn, Shinjuku Ku, Tokyo 1698555, Japan
[4] Japan Sci & Technol Agcy JST, Kawaguchi Ctr, Precursory Res Embryon Sci & Technol PRESTO, Kawaguchi, Saitama 3320012, Japan
关键词
Mesoporous Material; Mesoporous Film; Surfactant Assembly; Titania; Anatase; THIN-FILMS; NANOCRYSTALLINE ANATASE; SURFACE-AREA; TIO2; SILICA; TEMPLATE; HYBRIDS; SPHERES; DESIGN; CARBON;
D O I
10.1166/jnn.2011.4229
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Here we report synthesis of ordered mesoporous titania films with various amounts of Ga content. The influence of Ga contents on mesostructural ordering, surface morphology, thermal stability, and anatase crystallinity is carefully investigated, by using grazing incidence small angle X-ray scattering (GISAXS), transmission electron microscopy (TEM), field emission scanning electron microscopy (FE-SEM), and Raman spectroscopy. The presence of highly dispersed Ga contents in the titania frameworks can promote the thermal stability of mesoporous titania structures, resulting that the anatase crystallization successfully proceeds without collapse of mesostructures.
引用
收藏
页码:6926 / 6933
页数:8
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